Добавил:
Upload Опубликованный материал нарушает ваши авторские права? Сообщите нам.
Вуз: Предмет: Файл:
9_interface Sc_Ti_V ПРАВКАA5.doc
Скачиваний:
0
Добавлен:
01.07.2025
Размер:
357.89 Кб
Скачать

Physical properties Scandium subgroup

Sc

Y

La

Ac

density, g/сm3

3.0

4.5

6.2

10.1

tm, oС

1539

1509

920

1050

tb, oС

2727

2927

3469

3300

Rа, nm

0.164

0.181

0.187

0.203

R3+, nm

0.083

0.097

0.104

0.111

Stable nuclides

(100 %)

(100 %)

(99.91 %)

-

Ionisation energy

Е ® Е+, kJ∙mol-1

Е+ ® Е2+, kJ∙mol-1

Еo3+ + 3е = Е), V

-2.08

-2.37

-2.52

-2.60

Y, La, and Ac are silvery white metals. Sc has a yellowish colour. Sc аnd Y don`t corrode in normal conditions in dry air. La and Ac quickly become dark due to the thin oxide (hydroxide) film formation. Radioactive actinium glowes in the dark with a blue light.

Titanium subgroup

Ti

Zr

Hf

density, g/сm3

4.50

6.45

13.1

tm, oС

1668

1855

2220

tb, oС

3330

4340

4600

Ti3+/Ti

Zr4+/Zr

Hf4+/Hf

Еo3+ + 3е = Е), V

-1.76

-1.43

-1.57

Titanium subgroup elements are silvery white malleable metals. Titanium belongs to light metals; Zr and Hf are heavy metals. All are refractory. Pure metals are easily subjected to a mechanical processing. On the other hand, they can be hard and brittle at absorbance of small amounts of О2 and N2 (for instance, after thermal processing). Therefore, their welding is only possible using argon-arc method. Ti, Zr, and Hf absorb Н2 significantly. They form phases of insertion.

Vanadium subgroup

V

Nb

Ta

Colour

Steel-gray

Light-gray

gray

Rа, nm

0.134

0.146

0.146

R5+, nm

0.059

0.066

0.066

Ionisation energy

Е0 Е+, еV

6.71

6.88

7.88

density, g/сm3

5.96

8.57

16.6

tm, oС

1900

2470

3015

tb, oС

3400

4760

5500

V, Nb, and Ta are refractory metals with a volume-centred cubic unit cell. Their colour is usually silvery-gray and after oxidation of the surface it becomes dark. The chemical characteristics, properties of Ta and Nb are very similar since practically identical are their ionic and atomic radii. V, Nb, and Ta have high mechanical strength and malleability. When admixtures (O, N, C, B, H and other additives) are present they became brittle and hard because of compounds of varying composition with non-metals that are formed.

Соседние файлы в предмете [НЕСОРТИРОВАННОЕ]