
- •Lesson (1) Chemistry and measurement
- •Importance: Measurement of the masses of substances
- •Volumetric flask: made of "Pyrex glass", on its top there's a mark determining its volume capacity, It's used in the preparation of solutions with certain concentrations accurately.
- •Importance: Transport of solutions and measurement of their volumes.
- •Importance: It plays an important role in chemical and biochemical reactions.
- •Fig. (9) pH meter Lesson (2) Nanotechnology and Chemistry
- •Fig. (10) Different nanogold colours
- •Fig. (11) Nano copper
- •Fig. (12) Thin films
- •Fig. (13) Nanowires
- •Multi-walled tubes single-walled tube
- •Fig. (14) The design of a Buckyball
- •In Agriculture
- •In medicine
- •In the field of energy
- •In industry
- •It may worsen the problems of social and economic inequality, and the unfair distribution of technology and wealth.
- •The end of Chapter (1) Good Luck
- •The mass of matter (in grams)
- •The mass of one mole (gm/mole)
- •It helps us calculate the amounts of substances required for chemical reaction
- •Ionic reactions
- •In neutralization reactions, we don't need to write the signs of ions in their ionic reactions.
- •If one mole of oxygen produces 2 moles of water(36 grams of water)
- •Some laws on gases and moles
- •In other words, The volumes of reactant gases and the products are inversely proportional, which means that:-
- •Lesson (2) The calculation of chemical reactions
- •Nitrogen : Oxygen
- •Actual and theoretical yields
- •100 X Practical yield
- •39.4 Gm of solid barium sulphate BaSo4 precipitated when 40 gm of barium chloride solution BaCl2 reacted with potassium sulphate. Calculate the percentage yield of barium sulphate
- •2 Moles of BaCl2 2 moles of BaSo4
- •0.19 Mole of BaCl2 0.19 mol of BaSo4
- •In order to get the required amounts of products
- •The Answers
- •1 Mole of calcium carbonate 1 mole of calcium oxide CaO
- •0.5 Mole of calcium carbonate 0.5 mole of calcium oxide CaO
- •2 Moles of hydrogen 2 moles of water
- •1 Mole of oxygen 2 moles of water
- •2 Moles of oxygen 4 moles of water
- •0.25 Mole of Na2co3 0.25 mole of water
- •0.25 Mole of Na2co3 0.25 mole of carbon dioxide
- •The Answers
- •Lesson (1) solutions and colloids
- •Water and oil (suspension) Milk (colloid)
- •Cobalt chloride solution
- •Some important concepts
- •The process of salt dissolution in water
- •It calculates the concentration of solutions in percent
- •Volume of solution (l)
- •Vapour pressure: The pressure exerted by vapour when it becomes in state of equilibrium with the liquid inside a closed container at constant temperature and pressure
- •Some examples on colloidal systems
- •Vapour pressure: The pressure exerted by vapour when it becomes in state of equilibrium with the liquid inside a closed container at constant temperature and pressure
- •Lesson (2) Acids and Bases
- •In 1923, The English scientist "Thomas Lowry" and Danish scientist "Johannes Bronsted" formulated their theory about acids and bases
- •Methyl orange
- •Phenolphthalein
- •PH indicator colour chart
- •Remember
- •Valence: The no. Of electrons gained, given, or shared by atoms
- •Indicators: weak acids and bases whose colours change by the change of solution
- •The Answers
- •The Answers
Cobalt chloride solution
The importance of solutions
1- They're essential for the biological processes inside living organisms
2- They're important for the occurrence of some chemical reactions
The substances forming solutions are regularly distributed in all the solution parts
True solution: A homogenous mixture of two or more substances
The substance which exists in greater amount in solutions are called" solvents", while substances that exist in smaller amounts and dissolve in solvents are called "solutes"
Solutions are classified according to the physical state of both solute and solvent
-
Examples
Solute type
Solvent type
Solution type
Air -
Natural gas-
gas
gas
gas
-Water vapour in air
- gasoline mixture in air
liquid
gas
gas
Naphthalene in air
solid
gas
gas
- Dissolved oxygen in water
- Fizzy drinks
gas
liquid
liquid
- Alcohol in water
- ethylene glycol(anti-freezing) in water
liquid
liquid
liquid
- salt of sugar in water
solid
liquid
liquid
-Hydrogen in palladium and platinium
gas
solid
Solid
- silver amalgam Ag(s) / Hg(l)
liquid
solid
Solid
- alloys (Nickel-chrome alloy)
solid
solid
Solid
Some important concepts
Electronegativity: The ability of atom to attract electrons
Polar bond: A type of covalent bond between two atoms in which electrons are shared unequally (the greater atom carries a negative charge)
Polar molecule: A Molecule which has a bond carrying molecular positive charge and another one carrying molecular negative charge
The bonds in water molecules are polar because the negative charge (electronegativity) of oxygen is greater than that of hydrogen. Thus, oxygen atom carries molecular negative charge, while hydrogen atoms carry molecular positive charges.
The angle between the two bond of water molecule equals 104.5◦
Design of water molecule (the angle between the two bonds = 104.5◦)
Electrolyte and non electrolyte solutions
Electrolytes: Substances whose solutions can conduct electric current via the movement of free ions
Electrolytes are divided into:-
Strong Electrolytes: Electrolytes that completely disassociate in water (all their molecules disassociate into ions) which makes them high conductors of electricity
Examples:-
Ionic compounds: sodium chloride (NaCl) and sodium hydroxide (NaOH)
Polar covalent compounds: Hydrochloric acid (HCl) (it conducts electricity if it's a solution, not in gaseous state)
When hydrochloric acid dissolves in water, positive hydrogen ions are produced and bond with water molecules forming hydronium (H3O+)
HCl (g) + H2O (l) H3O+ (aq) + Cl- (aq)
Weak Electrolytes: Electrolytes that partially disassociate in water (small no. of its molecules disassociate in water) which makes them low conductors of electricity
Examples:-
Acetic acid CH3COOH (vinegar)
Ammonium hydroxide (ammonia solution) NH4OH
Water H2O
Non electrolytes: Substances whose solutions cannot conduct electricity because of the absence of free ions
Examples on non electrolytes:-
Sugar
Ethyl alcohol (ethanol)
Dissolution process: The process in which the solute molecules disassociate into negative ions, positive ions, or separated polar molecules and then get surrounded by the molecules of solvent
Polar and ionic compounds dissolve easily in water, while non polar molecules (fats, oil, methane…etc) don't dissolve in water (but dissolve in
benzene).
To know how dissolution process occur, we should know that water molecules are in continuous motion due to their kinetic energy
When putting an ionic compound crystal (such as NaCl) in water, water molecules collide with the crystal and attract its ions. This process is the dissolution process
A true solution is composed of regularly-distributed ions or molecules whose diameters range from 0.01 nm to 1 nm. This makes the solution homogenous and allows light to penetrate it
When putting little sugar in water, the polar molecules of sugar gets separated and bond to those of water by hydrogen bond forming sugar solution