Thorium

Thorium

For crucibles.

History

(Thor, Scandinavian god of war) Discovered by Berzelius in 1828. Much of the internal heat the earth produces has been attributed to thorium and uranium. Because of its atomic weight, valence, etc., it is now considered to be the second member of the actinide series of elements.

Sources

Thorium occurs in thorite and in thorianite. Large deposits of thorium minerals have been reported in New England and elsewhere, but these have not yet been exploited. Thorium is now thought to be about three times as abundant as uranium and about as abundant as lead or molybdenum. Thorium is recovered commercially from the mineral monazite, which contains from 3 to 9% ThO2 along with rare-earth minerals.

Uses

The metal is a source of nuclear power. There is probably more energy available for use from thorium in the minerals of the earth's crust than from both uranium and fossil fuels. Any sizable demand from thorium as a nuclear fuel is still several years in the future. Work has been done in developing thorium cycle converter-reactor systems. Several prototypes, including the HTGR (high-temperature gas-cooled reactor) and MSRE (molten salt converter reactor experiment), have operated. While the HTGR reactors are efficient, they are not expected to become important commercially for many years because of certain operating difficulties.

Production

Several methods are available for producing thorium metal; it can be obtained by reducing thorium oxide with calcium, by electrolysis of anhydrous thorium chloride in a fused mixture of sodium and potassium chlorides, by calcium reduction of thorium tetrachloride mixed with

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Thorium

anhydrous zinc chloride, and by reduction of thorium tetrachloride with an alkali metal.

Thorium was originally assigned a position in Group IV of the periodic table.

Properties

When pure, thorium is a silvery-white metal which is air-stable and retains its luster for several months. When contaminated with the oxide, thorium slowly tarnishes in air, becoming gray and finally black. The physical properties of thorium are greatly influenced by the degree of contamination with the oxide. The purest specimens often contain several tenths of a percent of the oxide. High-purity thorium has been made. Pure thorium is soft, very ductile, and can be cold-rolled, swaged, and drawn. Thorium is dimorphic, changing at 1400C from a cubic to a body-centered cubic structure. Thorium oxide has a melting point of 3300C, which is the highest of all oxides. Only a few elements, such as tungsten, and a few compounds, such as tantalum carbide, have higher melting points. Thorium is slowly attacked by water, but does not dissolve readily in most common acids, except hydrochloric. Powdered thorium metal is often pyrophoric and should be handled carefully. When heated in air, thorium turnings ignite and burn brilliantly with a white light.

Uses

The principal use of thorium has been in the preparation of the Welsbach mantle, used for portable gas lights. These mantles, consisting of thorium oxide with about 1% cerium oxide and other ingredients, glow with a dazzling light when heated in a gas flame. Thorium is an important alloying element in magnesium, imparting high strength and creep resistance at elevated temperatures. Because thorium has a low work-function and high electron emission, it is used to coat tungsten wire used in electronic equipment. The oxide is also used to control the grain size of tungsten used for electric lamps; it is also used for high-temperature laboratory crucibles. Glasses containing thorium oxide have a high refractive index and low dispersion. Consequently, they find application in high quality lenses for cameras and scientific instruments. Thorium oxide has also found use as a catalyst in the conversion of ammonia to nitric acid, in petroleum cracking, and in producing sulfuric acid.

Isotopes

Twenty five isotopes of thorium are known with atomic masses ranging from 212 to 236. All are unstable. 232Th occurs naturally and has a half-life of 1.4 x 1010 years. It is an alpha emitter. 232Th goes through six alpha and four beta decay steps before becoming the stable isotope 208Pb. 232Th is sufficiently radioactive to expose a photographic plate in a few hours. Thorium disintegrates with the production of "thoron" (220Rn), which is an alpha emitter and presents a radiation hazard. Good ventilation of areas where thorium is stored or handled is therefore essential.

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Thorium

Cost

Thorium metal (99.9%) costs about $150/oz.

Sources: CRC Handbook of Chemistry and Physics and the American Chemical Society.

Last Updated: 12/19/97, CST Information Services Team

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Europium

Europium

For color TV tubes.

History

(Europe) In 1890 Boisbaudran obtained basic fractions from samarium-gadolinium concentrates which had spark spectral lines not accounted for by samarium or gadolinium. These lines subsequently have been shown to belong to europium. The discovery of europium is generally credited to Demarcay, who separated the rare earth in reasonably pure form in 1901. The pure metal was not isolated until recent years.

Production

Europium is now prepared by mixing Eu2O3 with a 10%-excess of lanthanum metal and heating the mixture in a tantalum crucible under high vacuum. The element is collected as a silvery-white metallic deposit on the walls of the crucible.

Properties

As with other rare-earth metals, except for lanthanum, europium ignites in air at about 150 to 180oC. Europium is about as hard as lead and is quite ductile. It is the most reactive of the rare-earth metals, quickly oxidizing in air. It resembles calcium in its reaction with water. Bastnasite and monazite are the principal ores containing europium.

Sources

Europium has been identified spectroscopically in the sun and certain stars. Seventeen isotopes are now recognized. Europium isotopes are good neutron absorbers and are being studied for use in nuclear control applications.

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Europium

Uses

Europium oxide is now widely used as a phospor activator and europium-activated yttrium vanadate is in commercial use as the red phosphor in color TV tubes. Europium-doped plastic has been used as a laser material. With the development of ion-exchange techniques and special processes, the cost of the metal has been greatly reduced in recent years.

Cost

Europium is one of the rarest and most costly of the rare-earth metals. It is priced about about $7500/kg.

Sources: CRC Handbook of Chemistry and Physics and the American Chemical Society.

Last Updated: 12/19/97, CST Information Services Team

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