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THERMODYNAMIC PROPERTIES

 

 

 

6.101

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

Mg(NO

 

 

 

3 )2

· 6H

2 O

MgO microcrystal

 

Mg(OH)

 

 

2

 

 

std. state

 

Mg

3

(PO

4 )2

 

 

MgS

 

 

 

 

 

 

MgSeO

 

 

4

 

 

std. state

 

Mg

2

Si

 

 

 

MgSiO

 

 

3

clinoenstatite

Mg

2

SiO

4 forsterite

Mg

3

Si 4 O

10

(OH)

2 talc

MgSO

 

 

3

· 3H

2 O

 

MgSO

 

 

3

· 6H

2 O

 

MgSO

 

 

4

 

 

 

std. state

 

MgSO

 

 

4

· H

2 O kieserite

MgSO

 

 

4

· 7H

2 O epsomite

MgTiO

 

 

3

 

 

 

Mg

2

TiO

4

 

 

MgTi

 

 

2 O

5

 

 

Mg

2

V

2 O

7 triclinic

MgWO

 

 

4

 

 

Manganese

 

 

Mn

 

 

 

 

 

 

Mn

2

std. state

MnBr

 

2

 

 

 

std. state

 

Mn

3

C

 

 

 

 

MnCl 2

 

 

 

std. state

 

MnCO

 

 

3

 

 

 

Mn

2

(CO)

10

 

 

MnF

 

2

 

 

 

 

MnI

 

2

 

 

 

 

Mn(NO

 

 

3 )2

 

 

std. state

 

MnO

 

 

 

 

 

 

MnO

 

 

2

 

 

 

Mn

2

O

3

 

 

 

MnO

 

 

 

 

 

 

 

 

4

 

 

 

MnO

 

 

2

 

 

 

 

 

4

 

 

 

Mn

3

O

4

 

 

 

Mn

3

(PO

4 )2

 

 

MnS

 

 

 

 

 

 

MnSe

 

 

 

 

 

 

MnSiO

 

3

 

 

 

MnSiO

 

4

 

 

 

MnSO

 

 

4

 

 

 

std. state

 

MnTiO

 

3

 

 

 

c

2613.3

2080.7

452

 

c

601.6(3)

569.3

26.95(15)

37.2

c

924.7

833.7

63.24

77.25

aq

926.8

769.4

149.0

 

c

3780.7

3538.8

189.20

213.47

c

346.0

341.8

50.3

45.6

c

968.51

 

 

 

aq

1066.1

896.2

84.1

 

c

77.8

77.1

81.6

67.9

c

1548.9

1462.0

67.8

81.9

c

2174.0

2055.1

95.1

118.5

c

5922.5

5543.0

260.7

321.8

c

1931.8

 

 

 

c

2817.5

 

 

 

c

1284.9

1170.6

91.6

96.5

aq

1376.1

1199.5

118.01

 

c

1602.1

1428.8

126.4

 

c

3388.71

2871.9

372

 

c

1497.6

1420.1

111.08

91.88

c

2164.0

2048

115.0

129

c

2509

2369

135.6

146.9

c

2835.9

2645.29

200.4

203.47

c

1516

1404

101.2

109.1

c

0

0

32.01

26.30

aq

220.75

228.1

73.6

50

c

384.9

372

138.1

75.31

aq

464.0

409.2

 

 

c

4.6

5.4

98.7

93.51

c

481.3

440.5

118.20

72.9

aq

555.05

490.8

38.9

222

c

894.1

816.7

85.8

81.5

c

1677.4

 

 

 

c

795.0

749

92.26

67.99

c

242.7

 

150.6

75.35

aq

331.0

 

 

 

c

576.26

 

 

 

aq

635.6

451.0

218.0

121.0

c

385.2

362.9

59.8

45.4

c

520.1

465.2

53.1

54.1

c

959.0

881.2

110.5

107.7

aq

541.4

447.3

191.2

82.0

aq

653.0

500.8

59

 

c

1387.8

1283.2

155.6

139.7

c

3116.7

 

 

 

c

214.2

218.4

78.2

50.0

c

106.7

111.7

90.8

51.0

c

1320.9

1240.6

89.1

86.4

c

1730.5

1632.1

163.2

129.9

c

1065.3

957.42

112.1

100.4

aq

1130.1

972.8

53.6

243

c

1355.6

 

105.9

99.8

6.102

 

SECTION

6

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

Mercury

Hg

 

 

 

Hg

2

 

 

Hg

 

 

 

HgBr

2

 

Hg

2 Br 2

 

Hg(CH

 

3 )2

Hg(C

 

2 H

5 )2

HgCl

2

 

Hg

2 Cl2

 

Hg(CN)

 

2

Hg

2 CO

 

3

HgC

2 O

4

HgF

2

 

 

Hg

2 F2

 

HgI

2

 

 

Hg

2 I2

 

 

Hg

2 (N

3 )2

HgO

 

 

 

HgS

 

 

 

HgSO

 

4

 

Hg

2 SO

 

4

HgTe

 

 

 

Molybdenum

Mo

 

 

 

MoBr

3

 

MoCl

4

 

MoCl

5

 

MoCl

6

 

Mo(CO)

 

6

MoF

6

 

 

MoO

 

2

 

MoO

 

3

 

MoO

 

2

std. state

 

4

MoS

2

 

 

Mo

2 S

3

 

Neodymium

 

 

Nd

 

 

 

Nd

3 std. state

NdCl

3

 

std. state

NdF

3

 

 

Nd(NO

 

3 )3

Nd

2 O

3

 

Neon

 

 

 

Ne

 

 

 

Neptunium

 

Np

 

 

 

NpF

6

 

 

NpO

2

 

 

lq

0

0

75.90(12)

28.00

g

61.38(4)

31.8

174.971(5)

20.8

aq

170.21(20)

 

36.19(80)

 

aq

166.87(50)

 

65.74(80)

 

c

170.7

153.1

172.0

75.3

c

206.9

181.1

218.0

104.6

lq

59.8

140.2

209

 

lq

30.1

 

 

 

c

224.3

178.6

146.0

73.9

c

265.37(40)

210.7

191.6(8)

102.0

c

263.6

 

 

 

c

553.5

468.1

180.0

 

c

678.2

 

 

 

c

405

362

134.3

74.86

c

485

469

161

100.4

c

105.4

101.7

180.0

77.75

c

121.3

111.1

233.5

105.9

c

594.1

746.4

205

 

c

90.79(12)

58.49

70.25(30)

44.06

c

58.2

50.6

82.4

48.4

c

707.5

594

 

 

c

743.09(40)

625.8

200.70(20)

131.96

c

42.0

 

 

 

c

0

0

28.71

24.13

c

284

259

175

105.4

c

477

402

224

128

c

527

423

238

155.6

c

523

391

255

175

c

982.8

877.8

325.9

242.3

lq

1585.66

1473.17

259.69

169.8

c

588.9

533.0

46.3

56.0

c

745.2

668.1

77.8

75.0

aq

997.9

836.4

27.2

 

c

235.1

225.9

62.57

63.56

c

270.3

278.6

181.2

109.3

c

0

0

71.6

27.5

aq

696.2

671.5

206.7

21

c

1041.0

 

 

113

aq

1197.9

1065.7

37.7

431

c

1657.0

 

 

 

c

1230.9

 

 

 

c

1807.9

1720.9

158.6

111.3

g

0

0

146.328(3)

20.786

c

0

0

 

29.46

c

1937

 

 

 

c

1029

979

80.3

66.1

 

THERMODYNAMIC PROPERTIES

 

 

 

6.103

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

Nickel

 

 

 

Ni

 

 

 

 

 

Ni

 

2 std. state

Ni(OAc)

 

2

std. state

NiBr

2

 

 

NiCl 2

 

 

 

 

std. state

Ni(CN)

2

. state

std4

Ni(CO)

 

4

 

NiC

2 O

4

 

NiF

2

 

 

 

NiI

2

 

 

 

Ni(NO

 

3 )2

 

 

 

std. state

NiO

 

 

 

 

Ni

 

2 O

3

 

 

NiOH

 

 

 

 

 

 

 

 

Ni(OH)

 

2

 

NiS

 

 

 

 

Ni

 

3 S

2

 

 

NiS

2

 

 

 

NiSO

 

4

 

 

 

 

std. state

NiSO

 

4

· 7H

2 O

NiWO

 

4

 

Niobium

 

 

 

Nb

 

 

 

 

NbBr

5

 

 

NbC

 

 

 

 

NbCl 5

 

 

NbF 5

 

 

NbI

5

 

 

 

NbN

 

 

 

 

NbO

 

 

 

 

NbO

 

2

 

 

Nb

2 O

5

 

 

NbOCl

3

 

Nitrogen

 

 

 

N atomic

 

N

2

 

 

 

 

N

3

 

 

 

NCl 3

 

 

 

NF

2

 

 

 

NF

3

 

 

 

H

2 NOH

 

 

 

N

2 F2

cis

 

 

 

trans

 

 

c

0

0

29.87

26.1

aq

54.0

45.6

128.9

 

aq

1025.9

784.5

44.4

 

c

212.1

 

 

 

aq

297.1

253.6

36.0

 

c

305.3

259.0

97.7

71.66

aq

388.3

307.9

15.1

 

aq

367.8

472.0

218

 

lq

633.0

588.2

313

404.6

g

602.9

587.2

410.6

145.2

c

856.9

 

 

 

c

651.5

604.2

73.6

64.1

aq

719.2

603.3

156.5

 

c

78.8

 

 

 

aq

164.4

149.0

93.7

 

c

415.1

 

 

 

aq

468.6

268.6

164.0

 

c

240.6

211.7

38.00

44.31

c

489.5

 

 

 

aq

287.9

227.6

71.0

 

c

529.7

447.3

88.0

 

c

82.0

79.5

53.0

47.1

c

216.0

210

133.9

117.7

c

131.4

124.7

72

70.6

c

872.9

759.8

92.0

138.0

aq

963.2

790.3

108.8

327.9

c

2976.3

2462.2

378.94

364.59

c

1128.4

 

118.0

136.0

c

0

0

36.4

24.67

c

556

508

258.8

147.9

c

138.9

136.8

34.98

36.23

c

797.5

683.3

210.5

148.1

c

1813.8

1699.0

160.3

134.7

c

268.6

 

343

155.6

c

236.4

205.9

34.5

39.0

c

405.8

392.6

48.1

41.3

c

796.2

740.5

54.5

57.45

c

1899.5

1765.8

137.3

132.0

c

879.5

782

159

120.0

g

472.68(40)

 

153.301(3)

 

g

0

0

191.609(4)

29.124

aq

275.1

348.2

107.9

 

lq

230.0

 

 

 

g

43.1

57.8

249.9

41.0

g

132.1

90.6

260.8

53.37

c

114.2

 

 

 

g

69.5

109

259.8

49.96

g

82.0

120.5

262.6

53.47

6.104

 

SECTION

6

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

N

2

F4

 

N

2

H

4

hydrazine

N H22

 

4

hydrazine-d 4

N H2

 

5 std. state

N

2

H

5

Br

 

 

std. state

N

2

H

5

Cl

 

 

std. state

N

2

H

5

Cl · HCl

N

2

H

5

OH

undissoc; std. state

N

2

H

 

5 NO 3

 

 

std. state

(N

 

2 H

5 )2 SO 4

 

 

std. state

NO

 

 

 

 

NOBr

 

 

NOCl

 

NOF

 

 

 

NOF

 

 

3

NO

 

 

2

 

NO

 

 

 

 

 

2

 

NO

 

 

2

Cl

NO

 

 

2

F

NO

 

 

3

 

NO

 

 

 

 

 

3

 

N

2

O

 

 

N

2

O

 

2

N O2

 

22 hyponitrite

N

2

O

 

3

N

2

O

 

4

N

2

O

 

5

NSF

 

 

 

Osmium

 

 

 

Os

 

 

 

OsCl 3

OsCl 4

OsF 6

OsO 4

Oxygen

O atomic

O

2

 

O

3

 

OF

2

O

2

F2

OH

Palladium

Pd

Pd 2 std. state

g

8.4

79.9

301.2

79.2

lq

50.6

149.3

121.2

98.84

g

81.6

150.9

248.86

55.52

aq

7.5

82.4

151

70.3

c

155.6

 

 

 

aq

128.9

21.8

233.1

71.6

c

197.1

 

 

 

aq

174.9

49.0

207.1

66.1

c

367.4

 

 

 

lq

242.7

 

 

 

aq

251.50

109.2

207.9

73.2

c

251.58

 

 

 

aq

215.10

28.91

297

 

c

959.0

 

 

 

aq

924.7

579.9

322

151

g

91.29

87.60

210.76

29.85

g

82.23

82.42

273.7

45.48

g

51.71

66.10

261.68

44.7

g

66.5

51.0

248.02

41.3

g

163

96

278.40

67.86

g

33.1

51.3

240.1

37.2

aq

104.6

32.2

123.0

97.5

g

12.6

54.4

272.19

53.19

g

109

66

260.2

49.8

g

69.41

114.35

252.5

46.9

aq

206.85(40)

111.3

146.70(40)

86.6

g

81.6

103.7

220.0

38.62

g

170.37

202.88

287.52

63.51

aq

17.2

138.9

27.6

 

g

86.6

142.4

314.7

72.72

lq

19.5

97.5

209.20

142.71

g

11.1

99.8

304.38

79.2

g

11.3

117.1

355.7

95.30

g

 

 

259.8

44.1

c

0

0

32.6

24.7

c

190.4

121

130

 

c

254.8

159

155

 

g

 

 

358.1

120.8

c

394.1

305.0

143.9

 

g

337.2

292.8

293.8

74.1

g

249.18(10)

231.7

161.059(3)

21.9

g

0

0

205.152(5)

29.4

g

 

142.7

163.2

238.92

g

24.5

41.8

247.5

57.11

g

18.0

61.42

268.11

54.06

aq

230.015(40)

157.28

10.90(20)

148.5

c

0

0

37.61

25.94

aq

149.0

176.6

184.0

 

 

THERMODYNAMIC PROPERTIES

 

 

 

6.105

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

PdBr

2

PdBr

42 std. state

PdCl 2

PdCl 42 std. state

Pd 2 H

 

PdO

 

 

PdS

 

 

PdS

2

 

Phosphorus

P white

 

red, V

P

2

 

 

P

4

 

 

PBr

3

 

PBr

5

 

PCl 3

 

PCl 5

 

PF 3

 

 

PF 5

 

 

PH

 

3

 

 

std. state

PH

 

4 Br

PH

 

4 Cl

PH

 

4 I

 

PH

 

4 OH undissoc; std. state

PI

3

 

 

PO

 

2

 

PO

 

3

 

PO

 

43 std. state

P 2O

74 std. state

(P

2 O 3 )2 dimer

P

4 O

10

 

POBr

 

3

POCl

3

POClF

2

POCl

2 F

POF

3

 

PSCl

3

PSF

3

 

P

4 S

3

 

Platinum

Pt

PtBr 2

PtBr 3

PtBr 4

c

104.2

 

 

 

aq

384.9

318.0

247

 

c

171.5

125.1

105

 

aq

550.2

416.7

167

 

c

19.7

5.0

91.6

 

c

85.4

 

56.1

31.5

c

75

67

46

 

c

81.2

74.5

80

 

c

0

0

41.09(25)

23.83

g

316.5(10)

280.1

163.1199(3)

20.8

c

17.46

12.46

22.85

21.19

g

144.0(20)

 

218.123(4)

 

g

58.9(3)

24.4

280.01(50)

67.16

lq

184.5

175.5

240.2

 

g

139.3

162.8

348.15

76.02

c

269.9

 

 

 

lq

319.7

272.4

217.2

 

g

227.1

267.8

311.8

71.8

c

443.5

 

 

 

g

374.9

305.0

364.6

112.8

g

958

937

273.1

58.69

g

1594.4

1520.7

300.8

84.8

g

5.4

13.4

210.24

37.10

aq

9.50

25.31

120.1

 

c

127.6

47.7

110.0

 

c

145.2

 

 

 

c

69.9

0.8

123.0

109.6

aq

295.35

211.88

190.0

 

c

45.6

 

 

 

g

279.9

281.6

252.1

39.5

aq

977.0

 

 

 

aq

1277.4

1018.8

220.5

 

aq

2271.1

1919.2

117.0

 

c

1640.1

 

 

 

c

3009.9

2723.3

228.78

211.71

c

458.6

 

 

 

g

389.11

390.91

359.84

89.87

lq

597.1

520.9

222.46

138.82

g

558.5

512.9

325.5

84.94

g

970.7

924.1

301.68

68.83

g

765.7

721.6

320.38

79.32

g

1254.0

1206

285.4

68.82

g

363.2

347.7

337.23

89.83

g

1009

985

298.1

74.55

c

155

159

201

146

c

0

41.63

25.87

 

c

82.0

 

 

 

c

120.9

 

 

 

c

156.5

 

 

 

6.106

 

SECTION

6

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

PtCl2

 

PtCl3

 

PtCl4

 

PtCl42

 

PtCl42

std. state

PtCl62

std. state

PtF 6

 

 

PtI 4

 

 

PtS

 

 

PtS 2

 

 

Plutonium

Pu

 

 

Pu 3

 

Pu 4

 

PuBr

 

3

PuCl 3

PuCl 4

PuF 3

 

 

PuF 4

 

 

PuF 6

 

 

PuH

2

 

PuH

3

 

PuI 3

 

 

PuO

 

 

PuO

2

 

Pu 2 O 3 beta

Pu(SO

 

4 )2

PuS

 

 

Pu 2 S 3

Polonium

Po

 

 

PoO

2

 

Potassium

K

 

 

K std. state

KOAc acetate

KAg(CN)

2

KAgCl 2

 

K2

AgI 3

 

KAlCl4

 

K3

AlCl6

 

K3

AlF6

 

KAl(SO

4 )2

K3

AsO 4

std. state

KBF4

 

 

std. state

KBH 4

std. state

c

123.4

 

117

 

c

182.0

134

151

 

c

3218

 

 

 

c

231.8

172

176

 

aq

499.2

361.5

155

 

aq

668.2

482.8

220.1

 

g

 

 

348.3

122.8

c

72.8

 

 

 

c

81.6

76.2

55.06

43.39

c

108.8

99.6

74.68

65.90

c

0

0

51.5

35.5

aq

579.9

587.9

163

 

aq

579.9

1490

 

 

c

831.8

804.6

192.88

107.86

c

961.5

892.7

159.00

102.84

c

1381

 

 

 

c

1552

1478.8

112.97

96.82

c

1732

1644.7

161.9

120.8

c

25.48

27.2

222.59

167.36

c

139.3

101.7

59.8

39.0

c

138

82.4

64.9

43.2

c

648.5

643.9

214.2

111.8

c

565

538.9

70.7

51.3

c

1058.1

1005.8

82.4

68.6

c

1715.4

1632.3

152.3

131.0

c

2200.8

1969.5

163.18

181.96

c

439.3

436.7

78.24

53.97

c

989.5

985.5

192.46

129.66

c

0

0

62.8

26.4

c

251

197

71

61.5

c

0

0

64.68(20)

29.60

lq

2.284

0.264

71.46

32.72

g

89.0(8)

 

160.341(3)

 

aq

252.14(8)

283.26

101.20(20)

21.8

c

723.0

 

 

 

aq

738.39

652.66

189.1

15.5

aq

18.0

22.2

297

 

aq

497.4

498.7

333.9

 

aq

686.6

720.5

458.1

 

c

97

1094

197

156.4

c

2092.0

1938

377

248.9

c

3358.1

 

284.5

221.1

c

2470.2

2240.1

204.47

192.92

aq

1645.27

1498.29

144.8

 

c

1887

1785

133.9

114.48

aq

1827.2

1770.3

285

 

c

227.4

160.2

106.31

96.57

aq

204.22

168.99

212.97

 

 

THERMODYNAMIC PROPERTIES

 

 

 

6.107

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

KBO

2

 

 

c

981.6

std. state

aq

1024.75

K2 B 4 O

7

 

c

3334.2

KBr

 

 

 

c

393.8

std. state

aq

373.92

KBrO

3

 

 

c

360.2

 

 

 

 

aq

319.45

KBrO

4

 

 

c

287.86

KCl

 

 

 

c

436.5

std. state

aq

419.53

KClO std. state

aq

359.4

KClO 2

std. state

aq

318.8

KClO 3

 

 

c

397.73

std. state

aq

356.35

KClO 4

 

 

c

432.8

std. state

aq

381.71

KCN

 

 

 

c

113.1

std. state

aq

101.7

K2 CO

3

 

 

c

1151.0

std. state

aq

1181.90

K2 C 2 O

4

 

c

1346.0

 

 

 

 

aq

1329.72

K2 CrO

 

4

 

c

1403.7

std. state

aq

1385.91

K2 Cr

2 O

7

 

c

2061.5

K2 CuCl 4

· 2H 2 O

c

1707.1

KF

 

 

 

c

567.2

std. state

aq

585.01

K3 Fe(CN)

6

c

249.8

std. state

aq

139.4

K4 Fe(CN)

6

c

594.1

std. state

aq

554.0

K formate

c

679.73

std. state

aq

677.93

K glycinate

aq

722.16

KH

 

 

 

c

57.72

K2 HAsO

 

4 std. state

aq

1411.10

KH 2 AsO

 

4

c

1180.7

std. state

aq

1161.94

KHCrO

 

4

std. state

aq

1130.5

KHCO

 

3

 

c

963.2

std. state

aq

944.33

KHC

2 O

4

std. state

aq

1070.7

KHF 2

 

 

c

927.7

 

 

 

 

aq

902.32

KHgBr

3

 

c

550.20

std. state

aq

545.6

K2 HgBr

4

 

c

963.6

std. state

aq

935.5

KHgCl

3

 

c

671.1

std. state

aq

641.0

923.4

79.98

66.7

962.19

65.3

 

3136.8

208

170.5

380.7

95.9

52.3

387.23

184.9

120.1

271.2

149.2

105.2

264.72

264.22

 

174.47

170.01

120.2

408.5

82.55

51.29

414.51

159.0

114.6

320.1

146

 

266.1

203.8

 

296.31

143.1

100.3

291.29

264.9

 

303.1

151.0

112.41

291.88

284.5

 

101.9

128.52

66.3

110.9

196.7

 

1063.5

155.5

114.44

1094.41

148.1

 

1295.8

200.12

145.98

1294.36

255.2

 

1882.0

291.2

219.2

1492.9

355.43

253.22

537.8

66.5

48.98

562.08

88.7

84.9

129.7

426.06

 

120.5

577.8

 

453.1

418.8

322.2

438.11

505.0

 

634.3

192

66.1

598.23

221.8

 

53.01

50.21

37.91

1281.22

203.3

 

1036.0

155.02

126.73

1036.54

218

 

1048.1

286.6

 

863.6

115.5

 

870.10

193.7

 

981.7

251.9

 

859.7

104.3

76.94

861.40

195.0

 

542.7

360

 

937.6

515

 

592.5

314

 

6.108

 

SECTION

6

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

K2 Hg(CN)

 

4

std. state

K2 HgI

4

 

std. state

KH 2 PO

4

 

std. state

K2 HPO

4

std. state

K2 H

2 P 2 O

7

K3 HP

2 O

7

KHS

 

 

 

std. state

KHSO

 

3

 

KHSO

 

4

 

std. state

KI

 

 

 

KIO 3

 

 

KIO 4

 

 

KMnO

4

 

K2 MoO

4

 

std. state

KNH

2

amide

KNO

2

 

 

std. state

KNO

3

 

 

std. state

K2 Ni(CN)

 

4 std. state

K2 O

 

 

 

KO 2

 

 

 

K2 O 2

KOCN cyanate std. state

KOH

std. state K2 PdBr 4

std. state K3 PO 4

std. state K4 P 2 O 7

K2 PtBr 4

std. state K2 PtBr 6

std. state K2 PtCl4

std. state K2 PtCl6

std. state K2 ReCl 6

std. state

c

32.2

 

 

 

aq

21.8

51.9

510

 

c

775.0

 

 

 

aq

739.7

778.2

565

 

c

1568.33

1415.95

134.85

116.57

aq

1548.67

1622.85

192.9

 

aq

1796.90

1655.78

171.5

 

c

2815.8

 

 

 

aq

2783.2

2576.9

368

 

aq

3032.1

2822.1

351

 

c

265.10

 

 

75.3

aq

269.9

271.21

165.3

 

aq

878.60

811.07

242.3

 

c

1160.6

1131.4

138.1

 

aq

1139.72

1039.26

234.3

63.0

c

327.9

324.9

106.3

52.9

aq

307.57

334.85

213.8

120.5

c

510.43

418.4

151.46

106.48

aq

473.6

411.3

220.9

 

c

467.23

361.41

175.7

 

aq

403.8

341.8

322

 

c

837.2

737.6

171.71

117.6

c

1498.71

 

 

 

aq

1502.5

1402.9

232.2

 

c

128.9

 

 

 

c

369.82

306.60

152.09

107.40

aq

356.9

315.5

225.5

 

c

494.63

394.93

133.05

96.4

aq

459.74

394.59

249.0

64.9

aq

136.8

94.6

423

 

c

361.5

322.1

94.1

83.7

c

284.9

239.4

122.5

77.53

c

494.1

425.1

102.0

110

c

418.65

 

 

 

aq

398.3

380.7

209.2

 

c

424.7

378.7

78.9

64.9

aq

482.37

440.53

91.6

126.8

c

938.1

 

 

 

aq

889.5

884.5

452

 

c

1950.2

 

 

 

aq

2034.7

1868.6

87.9

 

aq

3280.7

3052.2

293

 

c

915.0

 

 

 

aq

872.8

828.4

326.4

 

c

1021.3

 

 

 

aq

975.3

898.7

368

 

c

1054.4

 

 

180.2

aq

1003.7

928.0

360

 

c

1229.3

1078.6

333.9

205.60

aq

1171.8

1049.4

424.7

 

c

1310.4

1172.8

371.71

214.68

aq

1266.92

1156.0

460

 

 

THERMODYNAMIC PROPERTIES

 

 

 

6.109

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

KReO 4

std. state K2 S

std. state K2 S 2

KSCN

std. state

K2

SeO

3

 

std. state

K2

SeO

4

 

std. state

K2 SiF 6

std. state

K2 SiO 3

K2 SnBr 6

K2 SnCl 6

K2 SO

3

 

std. state

K2 SO

4

K2 SO

6

 

std. state

K2

S 2 O 3

 

std. state

K2

S 2 O 4

K2

S 2 O 7

K2

S 2 O 8

 

std. state

K2 S 4 O 6

std. state

KSO

3 F

 

K2 UO 4

 

KVO

4

 

std. state

K2 Zn(CN)

4

std. state

Praseodymium

 

Pr

 

 

Pr 3 std. state

Pr(OAc)

3

std. state

PrCl 3

std. state

Pr(NO 3 )3

Pr 2 O 3

Promethium

PmCl 3

Protactinium

Pa

Pa4

PaBr 4

PaBr 5

c

1097.0

aq

1039.7

c

380.7

aq

471.5

c

432.2

aq

474.5

c

200.16

aq

175.94

c

979.5

aq

1013.8

c

1110.02

aq

1103.7

c

2956.0

aq

2893.7

c

1548.1

c

1218.0

c

1477.0

c

1125.5

aq

1140.1

c

1437.8

aq

1414.0

c

1437.7

aq

1414.02

c

1173.6

aq

1156.9

aq

1258.1

c

1986.6

c

1916.10

aq

1849.3

c

1780.7

aq

1728.8

c

1159.0

c

1921.3

c

1154.8

aq

1140.6

c

100.0

aq

162.3

c

0

aq

704.6

aq

2147.52

c

1056.9

aq

1206.3

c

1229.3

c

1809.6

c

1054.0

c

0

aq

619.2

c

824.0

c

862

994.5

167.82

122.55

977.8

303.8

8.4

364.0

105.0

74.7

480.7

190.4

 

487.0

233.5

 

178.32

124.26

88.53

190.58

246.9

18.4

936.4

218.0

 

1002.9

222

 

1007.9

259.0

 

2798.7

225.9

 

2766.0

327.2

 

1455.7

146.1

118.4

1160.2

443.1

246.0

1333.0

366.5

246.0

1053.1

176

 

1321.4

175.6

131.5

1311.1

225.1

251.0

1319.6

175.5

131.3

1311.14

225.1

251

1089.1

272

 

1166.9

297

 

1791.6

255

 

1697.41

278.7

213.2

1681.6

449.4

 

1613.43

309.66

230.79

1607.1

462.3

24.3

1066.9

155

 

119.7

431

 

0

73.2

27.20

679.1

209.0

29.0

1805.56

164.9

 

 

 

100.0

1072.8

42.0

439.0

 

 

117.40

0

51.8

 

787.9

234.0

 

820

289

 

6.110

 

SECTION

6

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

PaCl4

PaCl5 Radium

Ra Ra2

RaCl2 std. state Ra(NO 3 )2

std. state RaSO 4

std. state Radon

Rn

Rhenium

Re

Re std. state ReBr 3

ReCl 3

ReCl 26 std. state

ReO

2

ReO

3

Re

2 O 7

Rhodium

Rh

RhCl 3

Rh 2 O 3

Rubidium

Rb

Rb std. state

Rb acetate

RbBO

2

RbBr

 

std. state

RbBrO

3

Rb 2 CO

3

std. state

RbCl

 

std. state

RbClO

3

std. state

RbClO

4

std. state RbF

std. state Rb formate RbHCO 3

std. state RbHF 2

std. state

c

1043.1

953.0

192.0

 

c

1144.7

1034.3

238.0

 

c

0

0

71

 

aq

527.6

561.5

54.0

 

aq

861.9

823.8

167.0

 

c

992

796.2

222

 

aq

942.2

784.1

347.0

 

c

1471.1

1365.7

138

 

aq

1436.8

1306.2

75.0

 

g

0

0

176.235

20.79

c

0

0

36.9

25.5

g

769.9

724.6

188.9

20.8

aq

46.0

10.1

230.0

 

c

167.0

 

 

 

c

264

188

123.9

92.4

aq

761

590

251

 

c

423

368

172

 

c

605.0

531

257.3

 

c

1240.1

1066.1

207.1

166.1

g

1100.0

994.0

452.0

 

c

0

0

31.51

24.98

c

299.2

 

 

 

c

343.0

 

110.9

104.0

c

0

0

76.78(30)

31.06

g

80.9(8)

53.1

170.094(3)

20.8

aq

251.12(10)

283.97

121.75(25)

 

aq

737.2

653.3

207.9

 

c

971.0

913.0

94.3

74.1

c

394.59

381.79

109.96

52.84

aq

372.71

387.94

203.93

 

c

367.27

278.11

161.1

 

c

1136.0

1051.0

181.33

117.61

aq

1179.5

1095.8

186.2

 

c

435.35

407.81

95.90

52.41

aq

418.32

415.22

178.0

 

c

402.9

300.4

151.9

103.2

aq

355.14

291.9

283.68

 

c

437.19

306.9

161.1

 

aq

380.49

292.59

303.3

 

c

557.7

 

75.3

50.5

aq

583.79

562.79

107.53

 

aq

676.7

635.1

213.0

 

c

963.2

863.6

121.3

 

aq

943.16

870.82

212.71

 

c

922.6

855.6

120.08

79.37

aq

901.11

862.11

213.8

 

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