
- •10.1 Polymers
- •10.2 Additives to Polymers
- •10.2.1 Antioxidants
- •10.2.2 Antistatic Agents
- •10.2.4 Coupling Agents
- •10.2.5 Flame Retardants
- •10.2.6 Foaming Agents (Chemical Blowing Agents)
- •10.2.7 Inhibitors
- •10.2.8 Lubricants
- •Table 10.1 Plastic Families
- •10.2.9 Plasticizers
- •10.2.10 Ultraviolet Stabilizers
- •10.2.11 Vulcanization and Curing
- •10.3 Formulas and Key Properties of Plastic Materials
- •10.3.1 Acetals
- •10.3.2 Acrylics
- •10.3.3 Alkyds
- •10.3.4 Alloys
- •10.3.5 Allyls
- •10.3.6 Cellulosics
- •10.3.7 Epoxy
- •10.3.8 Fluorocarbon
- •10.3.9 Nitrile Resins
- •10.3.10 Melamine Formaldehyde
- •10.3.11 Phenolics
- •10.3.12 Polyamides
- •10.3.13 Poly(amide-imide)
- •10.3.14 Polycarbonate
- •10.3.15 Polyester
- •10.3.16 Poly(methylpentene)
- •10.3.19 Polyurethane
- •10.3.20 Silicones
- •10.3.21 Styrenics
- •10.3.22 Sulfones
- •10.3.23 Thermoplastic Elastomers
- •10.3.24 Vinyl
- •10.3.25 Urea Formaldehyde
- •Table 10.2 Properties of Commercial Plastics
- •10.4 Formulas and Advantages of Rubbers
- •10.4.1 Gutta Percha
- •10.4.2 Natural Rubber
- •10.4.3 Chlorosulfonated Polyethylene
- •10.4.4 Epichlorohydrin
- •10.4.5 Nitrile Rubber (NBR, GRN, Buna N)
- •10.4.6 Polyacrylate
- •10.4.7 cis-Polybutadiene Rubber (BR)
- •10.4.8 Polychloroprene (Neoprene)
- •10.4.10 Polyisobutylene (Butyl Rubber)
- •10.4.11 (Z)-Polyisoprene (Synthetic Natural Rubber)
- •10.4.13 Poly(vinyl Chloride) (PVC)
- •10.4.14 Silicone Rubbers
- •10.4.15 Styrene-Butadiene Rubber (GRS, SBR, Buna S)
- •10.4.16 Urethane
- •10.5 Chemical Resistance
- •10.6 Gas Permeability
- •10.7 Fats, OIls, and Waxes
- •Table 10.8 Constants of Waxes

10.5 |
CHEMICAL RESISTANCE |
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TABLE 10.4 Resistance of Selected Polymers and Rubbers to Various Chemicals at 20 |
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C |
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The information in this table is intended to be used only as a general guide. The chemical resistance classifications |
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are E |
excellent (30 days of exposure causes no damage), G |
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good (some damage after 30 days), F |
fair |
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(exposure may cause crazing, softening, swelling, or loss of strength), N |
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not recommended (immediate damage |
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may occur). |
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Chemical |
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Acids, dilute or weak |
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Acids, strong and concentrated |
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Alcohols, |
aliphatic |
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Aldehydes |
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Alkalies, concentrated |
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Esters |
Ethers |
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Glycols |
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Hydrocarbons, aliphatic |
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Hydrocarbons, |
aromatic |
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Hydrocarbons, halogenated |
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Ketones |
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Oxidizing agents, strong |
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Polymers |
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Acetals |
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F |
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N |
F |
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N |
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N |
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N |
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N |
G |
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N |
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N |
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N |
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N |
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N |
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Acrylics: poly(methyl methacrylate) |
G |
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N |
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E |
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— |
N |
N |
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E |
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E |
G |
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N |
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N |
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N |
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N |
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Allyls: diallyl phthalate |
G |
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— |
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— |
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— |
N |
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— |
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— |
— |
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E |
G |
G |
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N |
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— |
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Cellulosics: cellulose-acetate-butyrate and cellulose- |
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F |
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N |
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N |
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N |
N |
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N |
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N |
G |
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F |
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N |
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N |
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N |
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— |
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acetate-propionate polymers |
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Fluorocarbons |
E |
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E |
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E |
E |
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E |
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E |
E |
E |
E |
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E |
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E |
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E |
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E |
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Polyamides |
N |
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N |
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G |
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E |
E |
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G |
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— |
G |
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G |
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F |
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F |
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G |
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N |
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Polycarbonates |
G |
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N |
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G |
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F |
N |
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N |
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N |
G |
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N |
N |
N |
N |
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N |
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Polyesters |
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G |
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G |
N |
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— |
N |
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N |
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F |
G |
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G |
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F |
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F |
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N |
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F |
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Poly(methyl pentene) |
E |
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E |
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G |
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G |
E |
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G |
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N |
E |
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F |
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G |
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N |
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F |
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F |
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Low-density polyethylene |
E |
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E |
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E |
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G |
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E |
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G |
N |
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E |
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F |
F |
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N |
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G |
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F |
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High-density polyethylene |
E |
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E |
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E |
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E |
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E |
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G |
N |
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E |
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G |
G |
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N |
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G |
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F |
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Polybutadiene |
G |
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F |
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E |
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— |
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— |
— |
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— |
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— |
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E |
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E |
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E |
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— |
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64.10

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Chemical |
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Acids, dilute or weak |
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Acids, strong and concentrated |
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Alcohols, aliphatic |
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Aldehydes |
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Alkalies, concentrated |
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Esters |
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Ethers |
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Glycols |
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Hydrocarbons, aliphatic |
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Hydrocarbons, |
aromatic |
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Hydrocarbons, |
halogenated |
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Ketones |
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Oxidizing agents, strong |
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Polymers |
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Polypropylene and polyallomer |
E |
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E |
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E |
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E |
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E |
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G |
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N |
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E |
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G |
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F |
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N |
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G |
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F |
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Polystyrene |
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N |
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N |
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E |
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— |
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N |
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N |
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— |
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E |
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N |
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N |
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N |
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N |
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N |
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Styrene-acrylonitrile copolymers |
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— |
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— |
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N |
— |
N |
— |
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— |
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F |
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N |
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— |
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— |
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— |
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— |
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Styrene-acrylonitrile-butadiene copolymers |
— |
N |
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G |
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— |
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G |
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N |
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— |
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— |
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F |
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N |
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N |
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N |
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— |
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Sulfones: polysulfone |
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G |
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N |
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F |
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F |
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E |
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N |
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F |
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G |
F |
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N |
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N |
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N |
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G |
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Vinyls: poly(vinyl chloride) |
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E |
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G |
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E |
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G |
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G |
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N |
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F |
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F |
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G |
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N |
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N |
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N |
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G |
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Rubbers |
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Natural rubber |
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— |
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— |
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E |
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— |
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— |
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N |
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N |
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E |
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N |
N |
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N |
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N |
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— |
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Nitrile rubber |
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— |
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— |
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E |
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— |
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— |
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N |
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G |
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E |
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E |
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N |
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N |
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N |
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— |
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Polychloroprene |
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— |
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— |
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E |
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— |
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— |
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N |
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F |
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E |
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F |
N |
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N |
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N |
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— |
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Polyisobutylene |
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— |
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— |
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E |
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— |
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— |
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F |
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F |
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E |
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N |
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N |
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N |
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N |
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— |
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Polysulfide rubbers: Thiokol |
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— |
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— |
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E |
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— |
— |
E |
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E |
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E |
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E |
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F |
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N |
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N |
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— |
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Styrene-butadiene rubber |
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— |
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— |
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E |
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— |
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— |
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N |
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N |
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E |
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N |
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N |
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N |
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N |
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— |
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65.10