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Новые достижения в химии и химической технологии растительного сырья. Материалы II всероссийской конференции [2005]

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.(2-,+%,: *2!('%,0!( +( 7-,'")"%& (00#"),'*%(8 *%!(<-(+2,',<, )":0!'(8 +(,#,<(>"02( *2!('%&9 '"?"0!' ',)%&9 A20!-*2!,' 04*<%,'. E00#"),'*%(8 7-,',)(#(0$ ' ,!%,1"%(( %*(+,#"" -*07-,0!-*%"%%&9 ',3+6)(!"#": )".*!,.(2,3,': Trychophyton rubrum, T. mentagrophytes, Microsporum canis. H"36#$!*!& )":0!'(8 06..*-%&9 2,.7#"20,' (3 04*<- %,'&9 .9,' ,2*3*#(0$ +#(32( 2 7-,!(',<-(+2,',: *2!('%,0!( 7-"7*-*- !,' (<-(3",46#$'(%, %(0!*!(%, %(!-,46%<(%, 0*%<'(-(!-(%), 1(-,2, (0- 7,#$36".&9 '-*>*.( )#8 #">"%(8 !-(9,4(!(( ( .(2-,07,-((. I*('&0- 1(: 6-,'"%$ *2!('%,0!( ' -"36#$!*!" A207"-(."%!*#$%&9 (00#"),'*%(: + 60!*%,'#"% )#8 ',)%,<, A20!-*2!* (3 0&-$8 ,#(<,!-,4%,<, ."3,<(<- -,4(!* S. fuscum (1,9–0,48 .2</.#), %*(."%$1(: *%!(<-(+2,'&: A44"2! )#8 ,#(<,."3,!-,4%,<, <(<-,4(!* S. fallax (62,5–125 .2</.#) ( ."3,<(<-

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(8–9)

 

 

 

 

<(=#%&%*#.&7-

S. fuscum

 

S. capillifolium

 

 

 

S. wulfianum

 

 

(77–88)

 

 

S. russowii

 

 

 

 

 

S. girgensohnii

 

 

 

S. balticum

S. angusti-

S. centrale

S. fimbriatum

 

 

folium

 

 

 

 

 

 

 

 

S. compactum

S. contortum

S. flexuosum

>&%*#.&7-

 

S. jensenii

S. fallax

S. platyphyllum

 

S. lindbergii

S. obtusum

S. squarrosum

 

(89–93)

 

 

 

S. magellani-

S. subsecun-

 

 

 

 

 

 

 

 

cum

dum

 

 

 

 

S. papillosum

S. teres

 

 

 

 

 

S. warnstorfii

 

 

>&?*#%&%*#.&7-

 

S. majus

 

 

 

(94–103)

 

S. riparium

 

 

@*&3('/0&(. A 7/6$&B( #7)+7)71+C7 S. annulatum S. aongstroemii, S. cuspidatum, S. palustre, S. rubellum, 1)7*(7&1:&()9 1 #?0#3 ,97& #,&)/0&92.

!"#$%'%&

1.@#?7(*#6 D.@., E+6(B F.A. G)7#*&9 ,*&3(0(0&9 */)7(0&5 *#?/ Sphagnum 1 3(?&B&0( // H&3&"#-./*3/B(17&'()"&5 8+*0/$. 2002. 4. 36. I4. J. 27–29.

2.J/1&'-KC6&B"/9 J.G. @*&3(0(0&( )./%0#1#%# (7#*.90#%#) 32/ 1 3(?&B&0(

// @*&*#?/. 1943. I4. J. 41–50.

3.L/6(:&0/ K.>. J./%0#1-( 32& 4#3)"#5 #6$/)7& & ,(*),("7&1- &2 ,*&3(- 0(0&9 1 3(?&B&0(: D17#*(.. ?&). … "/0?. 6$. 0/+". 4#3)", 2002. 19 ).

4.KM1#1 N.D. O P"#$#%&& )./%0#1-2 32#1 4#3)"#5 #6$/)7& // @*#6$(3- P"#- $#%&&. 4#3)", 1973. 4. 3. J. 91–98.

5.<+$M?&9*#1 F.Q. O P"#$#%&& )./%0#1-2 32#1 4#3)"#5 #6$/)7& // R7(0&9 ,/397& N.D. KM1#1/: </7. II <(8*(%. P"#$. "#0.. 4#3)", 1998. J. 23–24.

6.L#*&)(0"# D.K. L*.$#*/ C%#-1#)7#"/ 4#3)"#5 #6$/)7&: D17#*(.. ?&). … "/0?. 6$. 0/+". 4#3)", 2002. 23 ).

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G$',*("* 0*41,"015& <$<#0#- -*.!1 '$,28$-", &*-9*0$&101 &*9- ,##@-*(("%$-", '0*-3 1/&$(#',*(# #9)&()- 91&*- " <$'"/"& #& %$7*/&'$ " %#,"7*/&'$ "/B#!(#4# %#-9#(*(&$. H":," ($ '$,28$B 1'*,"7"'$5& 9,#- 6$!2 %#(&$%&$ %#-9#(*(&$ / '$,28$-" " /#<!$5& &*- /$-)- !#9#,("&*,2- ()* '#<-#.(#/&" '#<!*=/&'"3 &0*("*-, !$',*("*- " &*-9*0$&10#=.

I$<#0#- -*.!1 '$,28$-" 1/&$($',"'$5& !$',*("* 5…6 $&-., / 9#- -#625 '/&0#*(()B &*9,##@-*(("%#' &*-9*0$&10$ 0*41,"01*&/3 80…90 ºD, '0*-3 #@0$@#&%" ($ '$,28$B /#/&$',3*& #%#,# 15 -"(.

651

!"#$%&", &' &'( )*#+,-, ./+" 012-0"+"3$45, %4" 01$ 64"7 01"$8- 9"-$4 -2:1'#72&4';$, 0"+$721&/9 7"+2<=+ >? 8 "-&")1272&&/7 ".- 1'*")'&$27 &")/9 '<4$)&/9 ;2&41").

@+, 01")21<$ )/-)$&=4"#" 012-0"+"32&$, ./+$ 01")2-2&/ 6<8- 021$72&4/ 0" $*=%2&$A 7"+2<=+,1&" 7'88")"#" 1'*721' (BBC) $ 8"1.;$"&&/9 8)"D84) >?, )/-2+2&&/9 $* &'4$)&"#" 4"1:', 0"-)21#&=- 4"#" ".1'."4<2 "0$8'&&/7 )/(2 80"8"."7. E <'%284)2 $89"-&"#" 8/- 15, $80"+5*")'+8, :12*21&/D 4"1: &$*$&&"#" 4$0' -12)28&"D #1=00/ 8" 84202&5A 1'*+"32&$, 25%.

@+, $88+2-=27/9 ".1'*;") (1 – $* 4"1:' .2* 012-)'1$42+5&"D ".- 1'."4<$, 2 – $* 8/15, ".1'."4'&&"#") ./+$ 0"+=%2&/ 802<41/ 0"#+"- F2&$, ) ".+'84$ 200…800 &7, G?-802<41/ ) -$'0'*"&2 400…4000 87 -1 $ "012-2+2&" <"+$%284)" <$8+/9 #1=00. H" $*=%2&&/7 0'1'7241'7 64$ 8"2-$&2&$, "4&282&/ < <+'88= >?. I2".9"-$7" "4724$45, %4" 8"-213'- &$2 <$8+/9 #1=00 ) ".1'*;2 2 012)/('24 '&'+"#$%&/D 0"<'*'42+5 -+, ".1'*;' 1 ) 1,2–1,3 1'*'.

H1$&$7', )" )&$7'&$2 )/8"<"7"+2<=+,1&/D 9'1'<421 841"2&$, >?, -+, '&'+$*' ./+' )/.1'&' 91"7'4"#1':$,. B24"-"7 #2+501"&$- <'AF2D 91"7'4"#1':$$ ./+$ "012-2+2&/ =8+")$, <'%284)2&&"#" $ <"+$%284)2&&"#" '&'+$*' ".1'*;") >?. G88+2-")'&$, 01")"-$+$85 &' 91"7'4"#1':2 :$17/ «Du Pont» 821$$ 8800, 8&'.32&&"7 JK- -242<4"1"7 8 -$'0'*"&"7 -+$& )"+& 190…360 &7. L/+$ "012-2+2&/ *&'%2&$, 7'88")/9 -"+2D "4-2+5&/9 :1'<;$D (4'.+. 1). M%2)$-2& 0"- +$-$80218&/D 9'1'<421 ".1'*;") 8 ($1"<$7 -$'0'*"&"7 BB: "4 1000 -" 100000 -'+54"& 8 7'<8$7=7"7 1'8012-2+2&$, (Mmax) 8000 -'+54"& -+, ".1'*;' 1 $ ~ 4000 -'+54"& -+, ".1'*;' 2.

M.1'."4<' 8=.841'4' "0$8'&&/7 80"8"."7 01$)"-$4 < 872F2&$A 7'<- 8$7=7' BBC ) 84"1"&= 72&5($9 *&'%2&$D, %4" &2 01"4$)"12%$4 012-0"- +"32&$A " -2841=<4$)&/9 01";288'9, 01"$89"-,F$9 ) 9"-2 )"*-2D84)$,.

C"1.;$"&&/2 8)"D84)' $*=%'+$85 ) 84';$"&'1&"D 8$84272: 4)21- -', :'*' >? )"-&/2 1'84)"1/ 8"+2D 724'++"). ? 01".'7 0120'1'4")

(0,5 #) -".')+,+"85 0" 100 7+ 84'&-'14&/9 1'84)"1"), 8"-213'F$9 )"*- 1'84'AF$2 <"&;2&41';$$ Nr6+, Zn2+, Pb2+ ) .$-$84$+$1")'&&"D )"-2

(<"&;2&41';$, 10…100 7#/+).

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652

!"#$% &'()* +#,")!"- + ./0!"0'#!"- 1"!2'!$./2+3&+ &'$/44/ + 5!/- 6'!+' /)#".72++ Q (&8/8 9:). ;/1#+&/4%!/3 /)#".72+3 (#".72+"!!/3 '&1"#$%) "<.')'434/#% # <"&"=%> *./0!'!+3 ?'!8&>./ 0 4+!'-!"- @".&'. A'5*4%$/$B C1#<'.+&'!$"0 <.+0')'!B 0 $/74+2' 2.

D5 C$+, )/!!B, #4')*'$, 6$" "7./7"$1/ +#,")!"8" #B.%3 7/."$'.- &+6'#1+& #<"#"7"& <.+0")+$ 1 <"0BE'!+> #".72+"!!"- '&1"#$+ 9: <" "$!"E'!+> 1 .3)* $3('4B, &'$/44"0. F"4*6'!!B' .'5*4%$/$B !/- ,")3$#3 0 ,"."E'& #""$0'$#$0++ # ./!'' <.')#$/04'!!B&+ 0 4+$'./$*-

.' (<" Zn + Pb).

D!$'.'# 0B5B0/'$ 0B#"1/3 #".72+"!!/3 '&1"#$% 9: <" "$!"E'- !+> 1 Cr, $'& 7"4'', 6$" ./##&/$.+0/4"#% 05/+&")'-#$0+' 9: # Gr 6+ 0 0+)' /!+"!/ Cr2 H7 2-.

A'/12+3 05/+&")'-#$0+3 9: + +, !/$.+'0B, #"4'- # ,."&"0"- 1+- #4"$"-, #"43&+ ,."&/ + /5"$!"- 1+#4"$"- <."+#,")+$ !'")!"5!/6!". I/74>)/'$#3 0"##$/!"04'!+' ,."&"0"- 1+#4"$B )" 3-0/4'!$!"8" ,."- &/. F"#4' "1"!6/!+3 .'/12++ 0 "#/)"1 0B</)/>$ ,."&"0B' #"4+ 8*&+- !"0B, 1+#4"$.

J/(!/3 ,/./1$'.+#$+1/ +##4')*'&B, <.'</./$"0 5/14>6/'$#3 0 $"&, 6$", 0"-<'.0B,, "!+ <.'"7./5*>$ 0.')!B' 0'='#$0/, $/1+' 1/1 #"4+ $3- ('4B, &'$/44"0 !'@$3!B, 5/8.35!'!+-, 0 7+"4"8+6'#1+ +!'.$!B', $.'. !' <.')#$/043>=+' "</#!"#$+ )43 "1.*(/>='- #.')B. J"-0$".B,, 7+"<."- $'1$".B ./5.*E/>$ *84'0")".")!B' 1"&<4'1#B !'@$+. J-$.'$%+,, C$+ <.'</./$B /1$+0!" #$+&*4+.*>$ ./50+$+' <"60""7./5*>='- 7+"$B.

K$" "#"7'!!" 0/(!" )43 <"./('!!B, *6/#$1"0, 8)' 7+"#""7='#$0" !/,")+$#3 0 )'<.'##+0!"&, *8!'$'!!"& #"#$"3!++ # "#4/74'!!B&+ @+- 5+"4"8+6'#1+&+ @*!12+3&+.

L/74+2/ 1. ;/##"0B' )"4+ "$)'4%!B, @./12+- 9:, <"4*6'!!B, +5 !/$+0!"8" $".@/ + #B.%3, "7./7"$/!!"8" 7/."$'.&+6'#1+& #<"#"7"&

H7./5'2

;n

;max

;w

 

 

 

 

1

2300

8000

66700

2

2300

4000

60000

L/74+2/ 2. G".72+"!!/3 '&1"#$% Q&/, (&8/8 9:) <" "$!"E'!+> 1 Gr, Zn, Pb

H7./5'2

Qmax (Zn)

Qmax (Pb)

Qmax (Gr)

 

 

 

 

1

9,6

30,2

28,8

2

12,6

38,8

36,4

653

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E-mail: bnk@icct.ru

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654

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655

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