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Springer Series in Materials Science 338
Rebeka Rudolf Peter Majerič Vojkan Lazić Karlo T. Raić
Advanced Dental Metallic Materials
Springer Series in Materials Science
Volume 338
Series Editors
Robert Hull, Center for Materials, Devices, and Integrated Systems, Rensselaer Polytechnic Institute, Troy, NY, USA
Chennupati Jagadish, National University, Canberra, ACT, Australia
Yoshiyuki Kawazoe, Center for Computational Materials, Tohoku University, Sendai, Japan
Jamie Kruzic, School of Mechanical and Manufacturing Engineering, UNSW Sydney, Sydney, NSW, Australia
Richard Osgood Jr., Columbia University, Wenham, MA, USA Jürgen Parisi, Udo W. Pohl, Department of Materials Science and Engineering, Technical
University of Berlin, Berlin, Germany Tae-Yeon Seong, Department of Materials Science and Engineering, Korea
University, Seoul, Korea (Republic of) Shin-ichi Uchida,
Industrial Science and Technology, Tsukuba, Ibaraki, Japan Zhiming M. Wang,
Electronic Science and Technology of China, Chengdu, China
Universität Oldenburg, Oldenburg, Germany
Research School of Physics and Engineering, Australian
Electronics and Manufacturing, National Institute of Advanced
Institute of Fundamental and Frontier Sciences, University of
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The Springer Series in Materials Science covers the complete spectrum of mate­rials research and technology, including fundamental principles, physical properties, materials theory and design. Recognizing the increasing importance of materials science in future device technologies, the book titles in this series reflect the state-of­the-art in understanding and controlling the structure and properties of all important classes of materials.
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Rebeka Rudolf · Peter Majeriˇc · Vojkan Lazi´c · Karlo T. Rai´c
Advanced Dental Metallic Materials
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Rebeka Rudolf
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Faculty of Mechanical Engineering University of Maribor Maribor, Slovenia
Pomurje Science and Innovation Centre Murska Sobota, Slovenia
Vojkan Lazi´c School of Dental Medicine University of Belgrade Belgrade, Serbia
Peter Majeriˇc Faculty of Mechanical Engineering University of Maribor Maribor, Slovenia
Karlo T. Rai´c Professor Emeritus, Faculty of Technology and Metallurgy University of Belgrade Belgrade, Serbia
ISSN 0933-033X ISSN 2196-2812 (electronic) Springer Series in Materials Science ISBN 978-3-031-47350-0 ISBN 978-3-031-47351-7 (eBook)
https://doi.org/10.1007/978-3-031-47351-7
© The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG 2024
This work is subject to copyright. All rights are solely and exclusively licensed by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors, and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
This Springer imprint is published by the registered company Springer Nature Switzerland AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland
Paper in this product is recyclable.
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Preface
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Due to their excellent mechanical and biological properties, the use of metallic mate­rials in Dentistry has continued since time immemorial. This trend is particularly pronounced in modern life. As alternative materials such as ceramics become increas­ingly popular, metallic materials are likely to continue to play an important role, due to their functional properties and proven excellent clinical responses in dental appli­cations. In that sense, this monograph aims to cover the most recent topics regarding the development and application of advanced dental metallic materials.
With examples that are the result of the authors’ long-term research, an attempt is made to bring the readers closer to the specific purpose of dental metallic mate­rials, which must meet criteria and properties such as biocompatibility, non-toxicity, resistance to corrosion, durability (long-term), appropriate strength and toughness, as well as corresponding values of modulus of elasticity.
Within the monograph, after the comprehensive introduction, the following are discussed: Frontiers in the stability of Titanium Implants, processing of Cobalt­Chrome Dental Alloys, prosperous Shape Memory Alloys, emerging Gold Dental Alloys and Nano Foils in Dental Joining Practice. The illustrative experimental outcomes contribute to a better understanding of the emerging requirements.
Maribor, Slovenia Belgrade, Serbia Maribor, Slovenia Belgrade, Serbia
Rebeka Rudolf
Vojkan Lazi´c Peter Majeriˇc Karlo T. Rai´c
v
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Contents
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1 Introduction ................................................... 1
1.1 Classification of Dental Alloys ............................... 3
1.1.1 Classification of Dental Casting Alloys .................. 5
1.2 Surface Oxide Film on Metallic Biomaterials in the Human
Environment ............................................... 7
1.3 Requirements that Must Be Met by Metal Implants .............. 9
1.3.1 Interaction Human Organism↔Metallic Implant ......... 9
References ..................................................... 11
2 Frontiers in the Stability of Titanium Implants .................... 13
2.1 Structure and Properties of Titanium and Titanium-Based
Alloys .................................................... 14
2.2 Applications of Titanium and Titanium Alloys in Dentistry ....... 19
2.2.1 Mechanical Properties ................................ 21
2.2.2 Elements of Choice of Alloying Elements of Titanium ..... 22
2.2.3 Formation of a Surface Oxide Layer on Titanium ......... 24
2.2.4 Elements of Production ............................... 27
2.3 Implant Osseointegration .................................... 28
2.4 Surface Modification of Dental Implants ....................... 31
2.4.1 Micro Level Surfaces ................................. 33
2.4.2 Surfaces with Nanostructures .......................... 34
2.4.3 Example of Etching .................................. 36
2.4.4 Example of Surface Sol-Gel Processing (SSP) ............ 37
2.4.5 Example Using a Variety of Methods and Materials ....... 38
2.5 Examples of Expertise ...................................... 41
2.5.1 Plasma Spraying Hydroxide Apatite Coatings
on Cp-Titanium Grade 2 Surfaces ...................... 41
vii
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viii Contents
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2.5.2 Corrosion on the Surface of a Titanium Substrate
Generated by a Combination of Alkaline and Heat
Treatment ........................................... 48
2.6 Dental Implant Antimicrobial Surface Engineering .............. 49
References ..................................................... 50
3 Processing of Cobalt-Chrome Dental Alloys ....................... 53
3.1 Introduction to Cobalt-Chrome Dental Alloys .................. 53
3.2 Development of Co–Cr Alloys ............................... 54
3.3 Production of Co–Cr Alloys .................................. 54
3.4 Physico-Chemical Properties ................................. 55
3.5 Corrosion-Resistant Properties ............................... 56
3.6 Possible Indications ......................................... 58
3.7 Fabrication Techniques of Dental Prostheses ................... 58
3.7.1 Precision Casting of Co–Cr Dental Alloys ............... 60
3.7.2 Milling of Co–Cr Dental Alloys ........................ 63
3.7.3 Additive Manufacturing of Co–Cr Dental Alloys ......... 65
3.7.4 Veneering of Co–Cr Dental Alloys ..................... 68
References ..................................................... 71
4 Prosperous Shape Memory Alloys (SMAs) ........................ 75
4.1 Introduction ............................................... 76
4.2 Shape Memory Mechanism .................................. 77
4.3 Nickel–Titanium Alloys ..................................... 78
4.3.1 Manufacture of Ni–Ti Alloys .......................... 80
4.4 Copper-Based Alloys ....................................... 82
4.5 Orthodontic Appliance by SMA NiTi Orthodontic Wire .......... 83
4.6 Examples of Expertise ...................................... 84
4.6.1 Comparison of Commercially Available NiTi
Orthodontic Wires ................................... 84
4.6.2 Experimental Continuous Casting of Nitinol ............. 89
4.6.3 Microstructure, Mechanical Properties and Corrosion
Behaviour of NiTi and CuAlNi Aalloys Prepared
by Continuous Casting ................................ 93
4.6.4 Stress Dependent Electrical Resistivity of Orthodontic
NiTi Wire ........................................... 107
4.6.5 Biocompatibility of Ni–Ti Wires ....................... 116
4.6.6 Biocompatibility of Rapidly Solidified Cu–Al–Ni
SMA Thin Ribbon ................................... 122
4.6.7 Deposition of an Atomic Layer of a TiO2 on Ni–Ti
SMAs/Corrosion Protection in a Simulated Body Fluid .... 122
References ..................................................... 124
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