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Файл:Chemistry, technology and properties of synthetic rubber. Tutorial
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Operating temperature -60/-50 to 100/130°C. Melting point:
eq. 167°C.
It has low coefficient of linear thermal expansivity. It is
chemically very resistant. Resistant to dilute acids and most alkalis,
detergents, oils, polar solvents. It is characterized by high weather
resistance. Resistant to UV radiation, ozone, moisture. Is well
processed.
Characteristics of unfilled brands (PP + EPDM):
Density (23°C): 0.90-1.10 g/cm3
Tensile strength (23°C): 14 - 20 MPa
Tensile modulus (23°C): 600 - 900 MPa
Shore A hardness (23°C): A55 - D50
Application
Automotive parts. Bumpers. The instrument panel.
Mudguards. Spoilers. Mats-pallets. Seals. Gaskets. Stubs. Suitcases.
Trade marks
Armlen PP SK (Polyplastic, Moscow)
Novolen (BARS, Moscow)
Adflex (Basell)
Astryn (Basell)
Catalloy (Basell)
Daelim Poly (Daelim)
Elastron TPO (Elastron)
Flexathene (Equistar)
Forflex (PolyOne)
Garaflex (Alpha Gary)
Hifax (Basell)
Higlass (Basell)
Keltan TP (SABIC EuroPetrochemicals)
Milastomer (Mitsui)
Mulfi-Flex TPO (Multibase)
Polytrope (A.Schulman)
Telcar (Teknor Apex)
Vistaflex (AES)
191
3.28 Thermoplastic Vulcanizate
Thermoplastic vulcanizate, Thermoplastic rubber (TPV, TPE-V,
TPR).
Properties
Crystallizable thermoplastic rubber-like material. Operating
temperature: from -60/-40°C up to +65/130°C. Compressive strength
is higher than that of styrenic thermoplastic elastomers (TPE-S).
TPV is characterized by a high fatigue strength, resistance to
alternate loads. It has a high chemical resistance. Resistant to water,
antifreeze, water salt solutions, dilute acids and alkalis. It has
dimensional stability. It is well colored (usually recommended
pigment concentrates based on PP, but it should be clarified from the
material suppliers). It undergoes ultrasonic, friction welding, etc.
Characteristics of unfilled brands:
Density (23°C): 0.94-0.97 g/cm3
Tensile strength (23°C): 2-28 MPa
Shore A hardness (23°C): A35-D65
Application
Large and complicated automotive parts. Coverage for the
pedals. Seals for windows, lights, etc. Bicycle seats. Flexible parts of
household and office equipment (including heat-resistant). Elastic
part of cell phones. Elastic computer keyboard casing. Mouse balls.
Rollers to feed paper in office equipment. Hoses, fittings and seals
for washing machines and dishwashers. The handles of hand tools.
Handles and elastic parts of the power tool (drills, etc.). Handles of
the construction tools (brushes, trowels, etc.). Flexible parts of the
kitchen tools (for automatic washing).
Trade marks
Armlen PP TEP (Polyplastic)
Kvartopren (Kvart, Kazan)
Dynaflex (GLS)
Enflex-V (Enplast)
Forprene (PolyOne)
Garaflex (Alpha Gary)
192
Nexprene (Solvay Engineered Polymers)
Plasmer (SK Chem)
Santoprene (ExxonMobil Chemical)
Sarlink (DSM Elastomers)
Uniprene (Teknor Apex)
193
BIBLIOGRAPHY
1. Chanda, Manas Industrial Polymers, Specialty Polymers, and
Their Applications / Manas Chanda, Salil K. Roy. - 2009
2. Rubber Technologist’s Handbook. Vol 2. / Edited by J. White,
S.K. De and K. Naskar. - Smithers Rapra Technology Limited, 2009
3. Rubber Basics / Edited by Richard B. Simpson. - Rapra
Technology Limited, 2002
4. Davletbaeva, I.M. Chemistry and Technology of Synthetic
Rubber. Tutorial / I.M.Davletbaeva, E.I. Grigoriev/ - KSTU, 2010
5. Averko-Antonovich, L.A. Chemistry and Technology of the
Synthetic Rubber / L.A. Averko-Antonovich, Yu.O. AverkoAntonovich, I.M. Davletbaeva, P.A. Kirpichnikov. - M.: KoloSS,
2008. – 357 p.
6. Kirpichnikov, P.A. Technological diagram manual of the main
production of the syntheric rubber industry. 2d ed. / P.A.
Kirpichnikov, V.V, Beresnev, L.M. Popova. – L.: Chimiya, 1986. –
224 p.
7. Greve, Heinz-Hermann Rubber, 2. Natural. Ullmann's
Encyclopedia of Industrial Chemistry / Heinz-Hermann Greve. Wiley-VCH, Weinheim, 2000.
8. Gronover, Christian Schulze Natural Rubber Biosynthesis and
Physics- Chemical Studies on Plant Derived Latex, Biotechnology of
Biopolymers / Christian Schulze Gronover, Daniela Wahler and Dirk
Prufer. - Ed. Magdy Elnashar, InTech, 2011.
194
9. Slack, Charles Noble Obsession: Charles Goodyear, Thomas
Hancock, and the Race to Unlock the Greatest Industrial Secret of
the Nineteenth Century / Charles Slack. - Hyperion, 2002.
10. B
RYDSON, J.A.
B
RYDSON,
1988.
Rubbery Materials and Their Compounds / J.A.
11. Morton, Maurice Rubber Technology / Maurice Morton. Springer, 1987. - 652 p.
12. Brandt, Heinz-Dieter Rubber, 5. Solution Rubbers. Ullmann's
Encyclopedia of Industrial Chemistry / Heinz-Dieter Brandt [et al.]. Wiley-VCH, Weinheim, 2011.
13. Feldman, Dorel Styrene Butadiene Rubber / Butadiene Rubber /
Dorel Feldman. - New York: Nexant, 2004.
14. Barbalata, Alla Synthetic polymers: technology, properties,
applications / Alla Barbalata. - Springer, 1996. - 392 p.
15. Kent, James A. Handbook of Industrial Chemistry and
Biotechnology (11 ed.) / James A. Kent. - Springer, 2006. - 1793 p.
16. Obrecht, Werner Rubber, 4. Emulsion Rubbers. Ullmann's
Encyclopedia of Industrial Chemistry / Werner Obrecht. - WileyVCH, Weinheim, 2012.
17. Lysova, G. А. Epichlorohydrin rubbers / G. А. Lysova, N.D.
Khovanskaya. - М., 1980.
18. Gorin, Yu. А. Synthetic rubber / Yu. A. Gorin [et al.]; ed. I.V.
Garmonov. - 2d ed.. -L., 1983. - p. 488.
195
19. Andreeva, I.N. Copolymers of ethylene. Encyclopedia of
polymers. Т. 3. / I.N. Andreeva. -М.: Soviet encyclopedia, 1977. p.
1011-1016.
20. Bratsyhin, Е.А. Technology of plastics / Е.А. Bratsyhin, E.S.
Shul'gina - L.: Chimiya, 1982. 328 p.
21. Kalinchev, E.L. Choice of plastics for goods making and service:
The handbook / E.L. Kalinchev, М.B. Sakobtseva. - L.: Chimiya,
1987. - 416 p.
22. Kamenev, Е.I. Plastics application / Е.I. Kamenev, G.F.
Myasnikov, М.P. Platonov. - L.: Chimiya, 1985. - 448 p.
23. Katsnelson, М.Yu. Plastics: Reference book / Katsnelson М.Yu.,
Balaev G.А. - L.: Chimiya, 1978. - 384 p.
24. Plastics casting / Ed. Т. Ossbald, L.-Sh. Tunga, P.J. Gremann.
Translation ed. by E.L. Kalinchev. - SPb: Professiya, 2006. - 712 p.
25. Mindlin, S.S. Technology of polymers production and plastics
thereof / S.S. Mindlin. - L.: Chimiya, 1973. - p. 108.
26. Nikolaev, А.F. Plastics technology / А.F. Nikolaev - L.: Chimiya,
1977. - 368 p.
27. Plastics technology / Ed. V.V. Korshak. - М.: Chimiya, 1985. 560 p.
28. Bhowmick, A.K. Miscellaneous thermoplastic elastomers.
Handbook of elastomers / A.K. Bhowmick; 2 nd edition; Ed. by A.K.
Bhowmick, H.L. Stephens. – N.Y., Basel: Marcel Dekker, 2001. - P.
479-514.
196
29. Biron, M. Thermoplastics and thermoplastic composites:
Technical information for plastic users / M. Biron - Elsevier Science,
2007. - 874 p.
30. Ethylene vinyl acetate copolymers (EVA, VAE) / Brit. Plast.
Rubb, 1989.
31. Handbook of engineering and speciality thermoplastics. In 4
volumes. V. 1. Polyolefins and styrenics / Ed. by J.K. Fink. Scrivener Publishing, John Wiley & Sons, 2010. - Р. 187-209.
32. Modern plastics handbook / Ed. by C.A. Harper. - McGraw-Hill,
2000. - P. 1.46-1.47.
33. Polymer handbook. 4 th edition / Ed. by J. Brandrup, E.H.
Immergut, E.A. Grulke. - John Wiley & Sons, 1999. - 2366 p.
34. Rees, H. Mold Engineering / H. Rees - Munich, Vienna, N.Y.,
Cincinnati: Hanser, Hanser Gardner, 2002. - 688 p.
35. Strong, A.B. Plastics: Materials and processing / A.B. Strong; 3
rd edition. - New Jersey: Pearson Education Inc., 2006. - P.236-237.
36. Vasile, C. Practical guide to polyethylene / C. Vasile, M. Pascu Rapra Technology Ltd., 2005. - 176 p.
37. Whiteley, K.S. Polyolefins. Ullmann's encyclopedia of industrial
chemistry / K.S. Whiteley [et al.]. - Wiley-VCH Verlag, 2002.
38. Sobolev, V. М. Industrial synthetic rubbers / V. М. Sobolev, I. V.
Borodina. - М., 1977. - p. 340.
39. Chvostik, G. М. Synthetic rubber / G. М. Chvostik; 2d ed. - L.,
1983. - p. 488.
197
40. Gum, Wilson Reaction Polymers / Wilson Gum, Wolfram Riese,
Henri Ulrich. - New York: Oxford University Press, 1992.
41. Harrington, Ron Flexible Polyurethane Foams / Ron Harrington,
Kathy Hock. - Midland: The Dow Chemical Company, 1991.
42. Oertel, Gunter Polyurethane Handbook / Gunter Oertel. - New
York: Macmillen Publishing Co., Inc., 1985.
43. Ulrich, Henri Chemistry and Technology of Isocyanates / Henri
Ulrich. - New York: John Wiley & Sons, Inc, 1996.
44. Woods, George The ICI Polyurethanes Book / George Woods. New York: John Wiley & Sons, Inc, 1990.
45. Randall, David The Polyurethanes Book / David Randall, Steve
Lee. - New York: Wiley, 2002.
46. Blackwell, J. The Structure of the Hard Segments in
MDI/diol/PTMA Polyurethane Elastomers / J.Blackwell, M.R.
Nagarajan, T.B. Hoitink. - Washington, D.C.: American Chemical
Society, 1981.
47. Blackwell, John Structure of the hard segments in polyurethane
elastomers / John Blackwell, H. Gardner Kenncorwin. - IPC
Business Press, 1979.
48. Blair, G. The Effect of Visible Light on the Variability of
Flexible Foam Compression Sets / G. Blair. - Orlando, Florida:
Center for the Polyurethane Industry, 2007
49. Cousins, Kieth Polymers for Electronic Components / Kieth
Cousins. - Rapra Technology, 2001. - p. 101.
198
TUTORIAL
I.M. Davletbaeva, D.V. Beskrovniy, O.R. Gumerova
CHEMISTRY, TECHNOLOGY
AND PROPERTIES OF SYNTHETIC RUBBER
Ответственный за выпуск Ю.Н. Зиятдинова
199
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исследовательского технологического университета
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