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Gp III Conoco

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Lubricant Behavior in Contact

High Pressure

R

Shear Rate

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Energy Efficiency

 

 

 

 

High Pressure

Characterized by low

power loss between

 

 

 

 

moving parts

 

 

Viscosity Index

140

130

120

110

4 cSt

100

90

80

Group I

Group II

Group III Group IV

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Cold Cranking Simulator

(@ -25 °C)

1800

1600

1400

1200

1000

800

600

400

200

0

4 cSt

Group I

Group II

Group III Group IV

NOACK Volatility

35

30

25

20

 

 

15

4 cSt

 

 

10

5

0

Group I

Group II

Group III Group IV

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Taking Advantage of Group III

Base Oils

Examples:

Passenger Car Engine Oil

GF-4 Specifications

ILSAC GF-4

Oil Thickening

ILSAC GF-3

 

ILSAC GF-2

 

Catalyst Protection

Sludge

OEM concerns:

longer fluid life

cleaner engines

emissions system protection.

 

 

 

 

 

 

 

 

 

 

Fuel Economy

Valvetrain Wear

 

 

 

 

 

 

 

 

 

 

 

 

Piston Deposits

GF-4 tests are much more challenging for formulators

Group II and Group III

5W-30 Formulations

Base Stock API

II

II & III

III

Category

 

 

 

Base Oil VI

102

120

130

 

 

 

 

 

 

 

 

Viscosity Modifier (%)

9.1

6.6

5.7

 

 

 

 

Noack Volatility (%)

21

14

12

 

 

 

 

 

 

 

 

 

 

 

 

Formulation CCS

6200

5500

5000

(cP @ -30 C)

 

 

 

 

 

 

 

 

 

 

 

Formulation

 

 

 

Kinematic Viscosity

11.5

10.5

10.5

(cSt @ 100 C)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Higher VI base oils lower the volatility of finished blends & require less viscosity modifier

Comparison of CCS for Motor Oil Products

@ -30 C

 

 

 

 

 

 

 

 

1800

25 C

 

 

 

 

 

 

 

 

1500

 

 

 

 

 

 

 

 

1200

@ -

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

900

 

 

 

 

 

 

 

 

 

600

 

 

 

 

 

 

 

 

 

300

 

0

 

 

 

 

 

 

 

0

 

5W-20

GF

 

GF

 

Group

 

Group

 

 

 

 

 

 

 

 

5W-30

-

-

 

 

 

 

3

 

4

 

II

 

III

 

Base Oil

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Group III base oil has an inherent advantage

Over Group II when formulating for GF-4

The Role of Base Oil in Fuel Economy

Friction Decreasing

 

0.1

 

 

 

 

Friction Coefficient

0.08

 

 

Group II

 

 

 

Group III

 

 

 

 

 

0.06

 

 

Group IV

 

0.04

 

 

 

 

0.02

 

 

 

 

100 °C, ~1.0 GPa, 50% SRR

 

 

 

 

 

 

 

 

 

 

0

 

 

 

 

 

 

0.001

0.01

0.1

1

10

Entrainment Speed (m/s)

Friction: Group II > Group III > Group IV

Using higher quality base oil provides an edge for fuel economy

Lower friction = Better Fuel Economy

Heavy Duty Engine Oils: PC-10

PC-10 oils will be significantly different from

Lower sulfur, Ash, phosphorus, & zinc

And…Noack volatility limit will be lowered from 15% to 13%.

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