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Мурманский арктический государственный университет

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W-M

Ba-L

Zn-L

Fe-L

Ti-K

Ca-K

K-K

S-K

P-K

Si-K

Al-K

Fe-L

V-K

Ti-K

Ca-K

K-K

S-K

Si-K

Al-K

Mg-K

Na-K

Pb-M

Ca-K

K-K

S-K

Si-K

Al-K

Mg-K

Na-K

O-K

C-K

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Fe-L

Ca-K

K-K

S-K

Si-K

Al-K

Mg-K

Na-K

F-K

O-K

Pm-L

Br-L

Zn-L

Fe-L

Ti-K

Ca-K

K-K

S-K

P-K

Si-K

Al-K

Br-L

Fe-L

Ti-K

Ca-K

K-K

P-K

Si-K

Al-K

Mg-K

Na-K

Fig. 2.8. Graphs of chemical composition of metals in individual Apatity plaster samples based on microscale studies

Tab. 2.1. The results of the Ap 01 sample microanalysis

Sample	C	N	O	F	Na	Mg	Al	Si	P	K	Ca	Ti	Fe
Ap01(1)_pt1	5.19		46.07	5.99			1.68	1.66	12.79		26.61
Ap01(1)_pt2	12.68		39.63		1.08	1.44	4.12	6.87	1.69		4.23		28.27
Ap01(1)_pt3	25.45	5.77	47.40	0.72		1.26	1.81	3.40	4.46		9.72
Ap01(1)_pt4	10.87		40.81		0.83	3.64	6.32	15.72		2.63	3.86		15.32
Ap01(1)_pt5	16.83	4.46	49.71	2.19	1.19	1.06	7.66	10.00			6.89
Ap01(1)_pt6	9.95		43.45		4.89		8.27	11.28		2.34	19.83
Ap01(1)_pt7	30.17		42.37				10.36	9.20					7.90
Ap01(1)_pt8	23.91	4.47	35.51		1.88		10.99	15.20		8.04
Ap01(1)_pt9	26.20		44.53			2.23	9.81	11.42			5.81
Ap01(1)_pt10	13.09		44.76	1.64	2.52	2.65	11.34	18.26		2.81	2.92
Ap01(1)_pt11	11.19		49.03	0.35	5.04		10.46	21.14			2.78
Ap01(1)_pt12	9.30		45.32	9.34	5.13	5.57	2.92	18.89		1.07	2.46
Ap01(1)_pt13	19.41	3.88	36.49		3.99	0.75	10.99	21.20			3.27
Ap01(1)_pt14	15.09		49.53			2.36	5.54	7.61			19.86
Ap01(1)_pt15	18.10		34.21		0.81	0.92	3.16	10.73			16.21	15.86
Ap01(1)_pt16	33.92		36.13			0.88	3.99	5.56	5.31		14.20
Ap01(1)_pt17	7.96		42.39		2.86	3.87	2.49	18.03			8.55		13.85
Ap01(1)_pt18	20.04		44.75		7.06	1.13	10.39	13.07		2.51	1.05
Ap01(1)_pt19	14.15		46.04	0.10	1.90	1.53	4.35	14.95		0.66	9.08	7.24
Ap01(1)_pt20	18.30	5.03	45.26	2.81	0.56	0.82	2.19	4.16	7.46		13.41
Ap01(1)_pt21	32.51	9.19	46.48			1.14	2.87	4.05	0.64		3.13
Ap01(1)_pt22	7.18		36.43		1.45	0.43	3.28	7.43		0.60	1.84		41.33
Ap01(1)_pt23	8.63		33.75		7.74	1.28	3.38	23.40			3.09		18.72
Ap01(1)_pt24	26.51		47.71			1.38	6.81	9.59			8.01
Ap01(1)_pt25	8.39		41.33			0.45	11.30	14.66			12.85		11.02
Ap01(1)_pt26	8.41		43.79			6.47	3.45	17.99			6.31		13.58

Tab. 2.2. The results of the Ap 02 sample microanalysis

Sample	C	O	F	Na	Mg	Al	Si	P	Cl	K	Ca	Ti	Fe	Zn	Br
Ap02(1)_pt1	2.63	51.23	2.50	0.62	0.57	5.13	18.22				19.09
Ap02(1)_pt2	3.15	45.22			0.60	1.10	11.83				38.10
Ap02(1)_pt3	2.73	39.67			0.88	6.59	9.69				26.01	1.26	13.18
Ap02(1)_pt4	2.47	44.69	2.03	0.44	0.65	8.38	10.90				30.45
Ap02(1)_pt5	6.30	55.82				0.99	5.95				30.95
Ap02(1)_pt6	4.84	36.75				3.69	10.00	1.06			7.29		32.72	3.66
Ap02(1)_pt7	10.73	49.83	1.55	0.79	0.54	5.61	12.06		0.40		12.67	5.82
Ap02(1)_pt8	3.22	37.57			0.56	7.18	9.57				32.84		9.06
Ap02(1)_pt9	3.98	42.12				1.01	9.34				12.86		30.70
Ap02(1)_pt10	4.94	41.48				1.80	11.83			0.88	14.38		24.68
Ap02(1)_pt11	2.94	37.23			0.45	3.65	13.09				39.38		3.26
Ap02(1)_pt12	4.91	40.29		0.69		2.10	36.30			1.76	13.95
Ap02(1)_pt13	6.91	58.35				0.54	4.91				29.29
Ap02(1)_pt14	2.51	40.62					8.13				48.74
Ap02(1)_pt15	5.33	47.46				0.82	6.71				39.68
Ap02(1)_pt16	4.34	41.99				0.72	9.32				43.63
Ap02(1)_pt17	6.91	56.05				1.29	6.02			0.62	29.12
Ap02(1)_pt18	3.37	51.64		0.79	0.71	3.63	20.93			0.94	10.10		7.89
Ap02(1)_pt19	2.86	43.64				1.19	10.14				42.17
Ap02(1)_pt20	4.16	55.62		1.12	1.13	2.31	25.50			1.13	9.05
Ap02(1)_pt21	5.91	53.57				1.08	6.78				32.66
Ap02(1)_pt22	3.70	37.45				0.83	8.58				16.00		33.43
Ap02(1)_pt23	2.41	45.74			0.67	5.84	14.03			0.63	19.42		11.28
Ap02(1)_pt24	7.13	55.55					6.58				28.18				2.56
Ap02(1)_pt25	6.60	55.28			0.14	0.42	6.72				30.83
Ap02(1)_pt26	3.87	46.74	5.88			2.25	23.55			0.79	16.93

Tab. 2.3. The results of the Ap 03 sample microanalysis

Sample	C	N	O	F	Mg	Al	Si	P	S	K	Ca	Ti	Fe	Zn	Br	Ba
Ap03(1)_pt1	4.37		32.36			0.70	1.74		7.78		6.23	2.61		13.23		30.98
Ap03(1)_pt2	3.07		29.04			0.82	2.32		9.53		3.98			7.68		43.56
Ap03(1)_pt3	4.03		15.61			1.31	2.77		2.71		7.31			15.95		50.31
Ap03(1)_pt4	3.23		28.48			1.04	2.06		9.46		3.77			10.02		41.93
Ap03(1)_pt5	6.12		31.19			1.13	2.44				12.69	2.64		43.79
Ap03(1)_pt6	3.64		24.65			1.08	2.07		7.40		5.89	3.27		10.10		41.90
Ap03(1)_pt7	6.03		42.05		0.73	3.23	6.64	1.63			11.25	5.13	4.53	18.78
Ap03(1)_pt8	5.73		29.75			0.78	2.59		3.56		10.29	4.60		25.71		16.98
Ap03(1)_pt9	7.54		36.96				11.70				26.16			11.75	5.88
Ap03(1)_pt10	5.13		43.70		3.82	7.45	10.19				8.09	1.47	11.71	8.45
Ap03(1)_pt11	8.29		36.36		1.37	6.57	20.26	0.56			12.65	2.45		11.49
Ap03(1)_pt12	14.38		44.40	0.86	0.84	1.92	5.70		0.55		15.55	2.49		13.30
Ap03(1)_pt13	6.30		39.35			2.20	5.35				22.90	10.20		13.71
Ap03(1)_pt14	5.72		32.53	0.71		2.52	12.44			0.88	37.26			7.94
Ap03(1)_pt15	8.74		42.87	0.45	0.88	2.62	12.48				17.54			14.42
Ap03(1)_pt16	8.20		40.67			2.74	7.16				22.38			18.85
Ap03(1)_pt17	11.80		43.82			2.43	7.89				19.61			14.45
Ap03(1)_pt18	8.04		46.74			2.72	8.73			1.68	24.65			7.45
Ap03(1)_pt19	5.24		36.49			1.61	4.29				33.84	3.49		15.04
Ap03(1)_pt20	5.73		36.76			1.94	4.84	0.94	4.01		13.30	15.33		17.15
Ap03(1)_pt21	5.87		43.34	0.43	0.36	3.86	9.42				22.32	3.38		11.02
Ap03(1)_pt22	7.46		38.40		0.98	3.20	8.09				16.46	13.46		11.94
Ap03(1)_pt23	4.05		34.47	0.00	0.66	2.06	5.17				27.20	16.44		9.96
Ap03(1)_pt24	19.94	5.06	38.78			0.99	2.37	0.75			6.49	15.99		9.61
Ap03(1)_pt25	7.35		51.14		0.98	5.21	20.81			0.84	5.73	2.02		5.92

Tab. 2.4. The results of the Ap 04 sample microanalysis

Sample	C	N	O	F	Na	Mg	Al	Si	P	K	Ca	Ti	Fe	Zn	Br
Ap04(1)_pt1	2.88		29.21				1.88	3.14			1.90		60.99
Ap04(1)_pt2	8.00		50.66	0.70	1.62	1.00	3.04	6.91		1.82	26.25
Ap04(1)_pt3	8.24		53.87		1.42	0.53	2.28	7.33		0.77	25.56
Ap04(1)_pt4	14.48		40.33		3.23			11.58			13.75		8.61		8.03
Ap04(1)_pt5	6.76		38.51		3.06	1.07	8.45	16.08	0.95	3.48	4.56		17.08
Ap04(1)_pt6	35.99	15.80	36.90				2.31	4.91			4.08
Ap04(1)_pt7	15.75		48.40	1.35	2.37		5.81	13.91			12.41
Ap04(1)_pt8	12.42		44.69		1.76		4.30	14.24		1.73	20.86
Ap04(1)_pt9	9.54		46.99		1.92	1.28	3.39	7.82	0.78		28.29
Ap04(1)_pt10	33.22		45.37	0.42	2.25		4.68	7.77		1.31	4.98
Ap04(1)_pt11	22.78		47.63	0.50			7.14	14.08	0.74	1.15	5.97
Ap04(1)_pt12	14.89		47.12		2.97		5.95	12.62		3.15	13.30
Ap04(1)_pt13	6.94		37.64		2.16	1.92	4.88	8.48		1.38	3.71		32.90
Ap04(1)_pt14	7.38		42.17	1.36	2.44	1.10	4.90	10.28		2.72	27.65
Ap04(1)_pt15	8.51		46.32	1.27	4.44		8.18	16.23	0.54	3.40	8.03	3.09
Ap04(1)_pt16	22.26		47.17	0.83	3.11	0.66	6.30	13.28		0.81	5.58
Ap04(1)_pt17	9.83		41.39			0.64	5.05	14.71		3.06	14.48		5.65	5.17
Ap04(1)_pt18	6.91		45.81		2.38	0.58	7.30	14.61		2.03	8.85		11.52
Ap04(1)_pt19	10.33		48.33	2.51		1.45	6.21	13.30		4.62	13.25
Ap04(1)_pt20	6.60		38.20			1.21	4.90	9.54	6.46	0.93	13.81		10.08	8.26
Ap04(1)_pt21	7.88		38.01	1.89			4.10	21.60		1.68	22.02			2.83
Ap04(1)_pt22	5.95		45.64		2.85	0.99	5.74	15.35		1.74	21.74
Ap04(1)_pt23	10.69		50.51	0.00	2.42		2.39	6.95			27.04
Ap04(1)_pt24	6.27		40.12	2.15	2.76	1.31	5.01	9.21		3.26	15.57	14.34
Ap04(1)_pt25	11.35		48.35	0.87	2.63	1.24	7.95	18.50		1.33	7.78

Tab. 2.5. The results of the Ap 05 sample microanalysis

Sample	C	O	F	Na	Mg	Al	Si	K	Ca	Fe	Br
Ap05(1)_pt1	3.18	43.74			2.51	9.23	16.25	0.85	4.79	19.45
Ap05(1)_pt2	8.96	48.22			1.59	8.01	16.82		16.40
Ap05(1)_pt3	6.51	42.20			1.73	8.26	14.68		20.12	6.49
Ap05(1)_pt4	30.29	48.01	1.17		0.95	4.40	7.17		8.00
Ap05(1)_pt5	7.28	39.22		0.58	1.39		11.77	2.03	24.60		13.13
Ap05(1)_pt6	8.02	52.84	1.58		1.55	7.27	21.55		7.19
Ap05(1)_pt7	13.42	52.08		3.03		9.10	22.37
Ap05(1)_pt8	2.24	41.78		1.31	4.68	5.93	17.79	0.85	6.00	19.41
Ap05(1)_pt9	8.57	50.66		1.70		7.68	15.43		15.96
Ap05(1)_pt10	3.66	49.69	0.26		7.29	9.87	20.94	0.96	7.34
Ap05(1)_pt11	7.38	51.20				5.62	14.39		21.41
Ap05(1)_pt12	3.96	45.64	0.00	4.65	1.03	10.18	29.74		4.81
Ap05(1)_pt13	6.56	48.80			9.34	9.34	13.96		11.99
Ap05(1)_pt14	8.42	49.43			0.88	6.89	10.70		23.67
Ap05(1)_pt15	16.50	48.90			1.87	8.36	16.25	1.69	6.44
Ap05(1)_pt16	7.03	51.68					4.07		32.92		4.29
Ap05(1)_pt17	5.84	53.81	2.65		1.37	9.76	18.65		7.93
Ap05(1)_pt18	8.66	50.90		2.23	1.30	7.33	16.69		12.89
Ap05(1)_pt19	7.80	48.96		2.54	2.44	8.64	19.91		9.72
Ap05(1)_pt20	8.65	50.18		1.67	1.31	8.21	16.83		13.14
Ap05(1)_pt21	4.95	42.68	0.38		0.62	3.47	6.81		41.11
Ap05(1)_pt22	12.00	48.17			1.76	11.43	18.88		7.76
Ap05(1)_pt23	9.91	36.12		1.49	1.16	8.42	25.62	13.00	4.29
Ap05(1)_pt24	4.49	42.29	0.71		1.52	4.65	11.43		34.91
Ap05(1)_pt25	8.44	47.09			1.45	7.84	13.87		21.32

Tab. 2.6. The results of the Ap 06 sample microanalysis

Sample	C	O	F	Na	Mg	Al	Si	S	K	Ca	Ti	Fe	Zn	Br	W	Pb	Ba
Ap06(1)_pt1	3.11	50.57	0.11		2.70	3.73	19.97	0.40		4.95	10.15		3.62			0.69
Ap06(1)_pt2	4.08	54.41	0.64		1.10	4.78	19.68			8.15	7.16
Ap06(1)_pt3	5.41	53.44	0.87		0.76	4.08	19.45		0.84	9.77	5.38
Ap06(1)_pt4	5.42	50.59	0.92				9.16			27.91				6.00
Ap06(1)_pt5	4.12	40.90			0.89	2.32	5.47			46.30
Ap06(1)_pt6	7.46	53.49	0.48			1.74	3.95			32.88
Ap06(1)_pt7	6.21	46.77	1.64	1.25	4.67	4.56	14.02			20.89
Ap06(1)_pt8	3.80	43.08				2.06	4.98			46.08
Ap06(1)_pt9	5.35	50.25		3.19	2.87	5.96	14.72			17.66
Ap06(1)_pt10	8.33	44.93		3.49	0.61	8.95	21.98			11.71
Ap06(1)_pt11	7.11	53.44	0.00		2.47	5.29	17.81			8.10			5.78
Ap06(1)_pt12	4.84	48.09			1.62	4.01	9.12			32.32
Ap06(1)_pt13	8.50	43.88	1.01	1.41	4.45	3.91	18.52			18.32
Ap06(1)_pt14	22.67	43.11					1.47			22.66	5.99		4.09
Ap06(1)_pt15	29.04	46.15					0.98			19.66	4.16
Ap06(1)_pt16	8.63	55.34					0.73			33.95			1.35
Ap06(1)_pt17	8.66	41.24				4.55	15.60			29.95
Ap06(1)_pt18	3.29	50.25	1.11		1.03	3.49	17.20	0.61		12.18	10.83
Ap06(1)_pt19	6.25	53.46				0.45	0.79			37.50					1.55
Ap06(1)_pt20	6.77	54.50					1.05			37.68
Ap06(1)_pt21	7.17	57.35					1.33			34.15
Ap06(1)_pt22	7.22	51.29				1.18	2.20			38.11
Ap06(1)_pt23	4.06	39.95		0.55		1.49	3.06			50.90
Ap06(1)_pt24	6.18	56.87		0.61	0.65	1.87	3.90			29.92
Ap06(1)_pt25	5.95	53.13			1.70	2.74	7.96			28.53
Ap06(2)_pt1	4.34	33.79			0.55	1.80	4.92	8.48		6.55	4.93						34.63
Ap06(2)_pt2	3.87	34.01	1.54			4.37	16.29			23.16	16.76
Ap06(2)_pt3	4.77	29.12			0.66	3.26	11.66			10.62	3.09	32.73	4.10
Ap06(2)_pt4	11.13	46.88		0.33	1.75		8.29			19.48	6.73			5.42
Ap06(2)_pt5	13.68	27.99	0.63		0.70	2.10	3.97			9.51	2.05		39.37
Ap06(2)_pt6	4.91	19.84				2.06	6.55			5.41	7.16	54.07

Tab. 2.7. The results of the Ap 07 sample microanalysis

Sample	C	N	O	F	Na	Mg	Al	Si	P	S	K	Ca	Ti	Fe	Zn	Ba	W
Ap07(1)_pt1	3.27		29.28					1.24		10.54		3.42				49.67	2.58
Ap07(1)_pt2	5.51		37.50				1.55	5.62	1.59	1.00		5.75		36.82	4.66
Ap07(1)_pt3	5.56		50.52	1.75			1.06	12.92				14.40	13.78
Ap07(1)_pt4	10.37		38.69			0.89	2.82	8.02	2.48			10.91	3.28	18.44	4.12
Ap07(1)_pt5	11.11		45.27	0.67	6.67		7.16	25.14				3.97
Ap07(1)_pt6	10.56		49.04	0.85	1.48	0.57	3.10	10.36				24.04
Ap07(1)_pt7	8.57		53.56	0.00	2.25	0.93	4.41	11.54				18.75
Ap07(1)_pt8	7.12		39.93				2.73	8.63				41.60
Ap07(1)_pt9	11.34	3.00	39.11			1.03	3.60	13.00				13.58		11.04	4.31
Ap07(1)_pt10	11.68		43.62	0.66		1.63	9.16	21.07			1.44	10.75
Ap07(1)_pt11	18.90		45.73				3.32	11.92				20.13
Ap07(1)_pt12	45.08		41.13				1.45	3.98	1.12	0.55		6.68
Ap07(1)_pt13	4.70		36.97				2.26	6.67				49.41
Ap07(1)_pt14	12.84		50.39		1.51		4.47	13.41				17.38
Ap07(1)_pt15	12.31		48.22		1.45	1.59	5.42	11.49				19.51
Ap07(1)_pt16	4.92		52.08		4.52		10.77	21.86				5.86
Ap07(1)_pt17	16.34	5.58	44.37	6.20		3.70	5.32	11.07			3.17	4.26
Ap07(1)_pt18	6.88		41.58		0.68	0.85	3.04	9.66		0.55		36.76
Ap07(1)_pt19	29.29	6.74	38.75		1.08	0.85	3.29	8.16				11.84
Ap07(1)_pt20	10.73	5.86	50.47				3.18	11.29				18.47
Ap07(1)_pt21	14.29		48.88	0.48		0.95	4.37	11.65				19.38
Ap07(1)_pt22	8.54		49.55				5.11	11.73				25.07
Ap07(1)_pt23	9.00		47.25				4.05	14.71				24.99
Ap07(1)_pt24	5.71		38.93				2.53	7.67				45.17
Ap07(1)_pt25	26.18	8.68	44.97		0.85		1.93	6.56				10.82

Tab. 2.8. The results of the Ap 08 sample microanalysis

Sample	C	N	O	F	Na	Mg	Al	Si	S	K	Ca	Ti	V	Fe
Ap08(1)_pt1	3.62		28.03				1.09	2.33			1.46	7.50	1.02	54.94
Ap08(1)_pt2	4.28		36.21			0.57	1.58	4.03			1.10	24.66		27.58
Ap08(1)_pt3	15.18		34.81			1.37	5.12	16.42		1.67	13.74			11.70
Ap08(1)_pt4	7.49		25.92		1.31	1.37	3.07	7.15						53.69
Ap08(1)_pt5	12.98		41.78			1.83	3.25	13.97			15.82	10.36
Ap08(1)_pt6	4.53		43.11		1.37	4.04	6.54	18.28			6.69			15.43
Ap08(1)_pt7	15.85	3.48	38.94		0.64	1.37	5.69	7.79			2.97			23.28
Ap08(1)_pt8	6.61		30.45		0.76		1.70	4.01			1.29			55.18
Ap08(1)_pt9	11.93		48.12		1.18	0.48	4.90	28.76			4.63
Ap08(1)_pt10	24.56		43.11	1.35	1.47	2.03	5.43	14.35		1.81	5.89
Ap08(1)_pt11	6.62		42.79		7.81		13.34	17.94		4.28	4.10			3.13
Ap08(1)_pt12	37.28	8.27	41.44		0.77	0.50	2.45	6.46			2.84
Ap08(1)_pt13	6.78		20.15			1.41	1.96	5.37			2.04			62.30
Ap08(1)_pt14	17.47		48.21		1.13	1.64	4.52	12.18			10.24			4.62
Ap08(1)_pt15	8.78		43.68	1.43	1.02	1.54	8.67	12.53			22.35
Ap08(1)_pt16	21.88		46.99				2.86	11.52			5.87			10.88
Ap08(1)_pt17	19.91		44.32		1.36	1.36	4.34	15.29			13.43
Ap08(1)_pt18	16.23	3.82	32.84			1.19	4.70	21.44			19.79
Ap08(1)_pt19	26.40		47.76		1.95	1.01	3.86	13.61	0.49		4.92
Ap08(1)_pt20	20.16		47.08		1.80	1.92	5.49	14.47		3.07	6.01
Ap08(1)_pt21	17.42		45.05		0.83	1.77	4.74	13.34			9.76			7.09
Ap08(1)_pt22	15.65		39.53		2.75	1.81	4.87	16.26			3.12			16.03
Ap08(1)_pt23	11.13		41.51				4.13	17.34		7.48	18.41
Ap08(1)_pt24	6.93		43.81			1.37	3.20	12.30		0.88	31.51
Ap08(1)_pt25	8.89		30.31		0.84	0.87	3.03	9.37			5.34	34.81		6.54

Tab. 2.9. The results of the Ap 09 sample microanalysis

Sample	C	O	Na	Mg	Al	Si	S	K	Ca	Pb
Ap09(1)_pt1	4.45	44.41	0.61	0.79	1.38	19.79		0.89	27.69
Ap09(1)_pt2	5.94	52.69	0.48	0.73		10.50	1.06		28.61
Ap09(1)_pt3	6.16	51.28	0.50	0.82	0.83	21.41			19.00
Ap09(1)_pt4	5.35	53.21		0.72	0.51	20.08			20.12
Ap09(1)_pt5	5.51	52.01	0.46	0.71	0.51	18.79			22.02
Ap09(1)_pt6	5.07	49.96		0.77	0.88	24.44		1.11	17.77
Ap09(1)_pt7	6.27	55.74		0.79	0.72	12.22	0.68		23.58
Ap09(1)_pt8	6.25	56.89				17.13			19.72
Ap09(1)_pt9	6.02	50.95	0.60	0.91	0.53	24.96			16.03
Ap09(1)_pt10	6.32	52.60	0.55	0.99		20.47	0.78		18.30
Ap09(1)_pt11	4.81	48.52				21.36	0.83		24.48
Ap09(1)_pt12	5.08	41.77		0.55	0.85	23.39			28.35
Ap09(1)_pt13	4.47	44.46		0.53	0.89	16.31	0.83		31.55	0.96
Ap09(1)_pt14	6.13	54.29	0.61	0.64	1.12	20.22		0.88	16.12
Ap09(1)_pt15	5.24	53.29		0.78	0.50	18.56	0.84		20.79
Ap09(1)_pt16	5.80	55.74		0.72		13.16			24.58
Ap09(1)_pt17	4.87	50.02		0.66	0.32	18.64			25.49
Ap09(1)_pt18	4.92	46.75		0.61	0.89	25.35	0.83		20.65
Ap09(1)_pt19	5.19	52.79		0.95		20.26	1.03		19.77
Ap09(1)_pt20	6.39	46.77		0.93		19.56			26.36
Ap09(1)_pt21	6.76	55.53		0.69	0.60	9.87	1.03		25.51
Ap09(1)_pt22	4.10	50.84	0.61	0.81	0.66	35.43	0.47		7.07
Ap09(1)_pt23	6.17	49.49		1.08		17.97			25.29
Ap09(1)_pt24	4.72	44.74		0.94	0.97	13.57			35.07
Ap09(1)_pt25	5.80	45.74			1.13	13.96	0.93		32.45

Tab. 2.10. The results of the Ap 10 sample microanalysis

Sample	C	N	O	F	Na	Mg	Al	Si	S	K	Ca	Fe
Ap10(1)_pt1	5.03		52.02			1.03	2.58	10.28			29.07
Ap10(1)_pt2	2.93		36.40			0.69	1.64	7.36			50.99
Ap10(1)_pt3	6.91		51.42				1.90	22.49			17.27
Ap10(1)_pt4	7.10		50.82				2.78	19.84			19.44
Ap10(1)_pt5	7.64		56.69		0.57	0.90	1.24	5.55			27.41
Ap10(1)_pt6	8.73		49.25		0.62	1.00	4.72	16.07		4.04	15.57
Ap10(1)_pt7	5.18		47.72				2.36	17.91			26.83
Ap10(1)_pt8	5.20		51.82		1.55	1.11	4.08	29.91			6.32
Ap10(1)_pt9	5.24		48.17			0.95	1.15	8.48		1.12	34.90
Ap10(1)_pt10	5.82		50.72			0.91	1.70	8.06			32.79
Ap10(1)_pt11	8.83		51.84				2.64	23.33			13.36
Ap10(1)_pt12	28.90	10.37	42.42		0.98		1.38	10.69	0.89		4.36
Ap10(1)_pt13	30.00	7.74	46.78				1.24	11.14	0.82		2.29
Ap10(1)_pt14	3.87		40.41				1.31	18.63			5.84	29.92
Ap10(1)_pt15	7.80		53.30			0.93	1.58	16.65		0.63	19.12
Ap10(1)_pt16	1.79		42.88			4.21	4.26	19.27			27.60
Ap10(1)_pt17	4.06		54.22			0.68	1.10	35.54			4.40
Ap10(1)_pt18	12.53		49.63				3.92	21.00			12.93
Ap10(1)_pt19	4.08		50.00	0.33	0.44	1.06	3.69	35.52		1.07	3.82

Ap10(1)_pt20	10.26		47.47				3.77	18.57			19.94
Ap10(1)_pt21	8.22		48.66				3.67	14.54			24.91
Ap10(1)_pt22	10.31		52.79					24.06			12.84
Ap10(1)_pt23	3.95		38.38			1.03	1.52	8.60			46.53
Ap10(1)_pt24	5.53		46.84		0.97	0.94	1.33	27.15		1.12	16.12
Ap10(1)_pt25	4.97		42.47		0.58	2.30	4.34	15.54		0.78	16.03	12.98

Tab. 2.11. The results of the Ap 11 sample microanalysis

Sample	C	O	F	Na	Mg	Al	Si	P	S	K	Ca	Ti	Fe	Zn	Br
Ap11(1)_pt1	7.30	17.67				1.24	2.08		14.18		9.36			48.17
Ap11(1)_pt2	9.13	20.22	0.30			1.59	2.69		14.01		7.42			44.64
Ap11(1)_pt3	7.81	14.22				1.37	1.48		16.38		7.60			51.14
Ap11(1)_pt4	4.62	36.33				2.02	2.77				47.41			6.85
Ap11(1)_pt5	6.36	45.11	1.08		0.40	1.80	3.51				25.95			15.78
Ap11(1)_pt6	5.89	45.57			0.52	1.39	1.98		0.50		39.77			4.38
Ap11(1)_pt7	7.30	37.13			0.90	2.23	7.41		3.79		11.14			30.09
Ap11(1)_pt8	6.64	28.29	1.12		0.70	3.62	2.91		1.73		12.42			42.57
Ap11(1)_pt9	4.33	38.01	0.38			1.99	3.43				44.08			7.78
Ap11(1)_pt10	6.37	38.52			0.70	2.63	4.43				29.73			17.62
Ap11(1)_pt11	11.19	51.67			0.42	1.57	3.07				28.14			3.95
Ap11(1)_pt12	6.55	52.14		2.98		4.16	8.45				25.72
Ap11(1)_pt13	9.92	48.96					5.97				25.51				9.64
Ap11(1)_pt14	7.94	41.57					2.38				25.47			19.89	2.76
Ap11(1)_pt15	5.49	46.07		3.00	1.31	10.74	16.66			1.62	9.19		5.92

Ap11(1)_pt16	5.35	46.68				3.45	10.76	1.51			28.39	2.22
Ap11(1)_pt17	4.46	45.70		1.88	3.78	4.24	16.47				10.05		13.41
Ap11(1)_pt18	11.54	43.46	0.00		0.35	1.47	2.33		0.83		25.18			14.84
Ap11(1)_pt19	10.55	52.59			0.46	5.81	6.95			2.28	17.10			4.26
Ap11(1)_pt20	6.98	47.49			1.09	2.60	4.62		0.92		36.29
Ap11(1)_pt21	5.51	36.52				2.39	4.03		1.71		36.86			12.98
Ap11(1)_pt22	10.02	36.89	0.50		0.67	2.07	4.04		4.78		17.35			23.67
Ap11(1)_pt23	6.73	47.93				1.34	2.66				36.55			4.79
Ap11(1)_pt24	5.55	42.41				1.73	2.30				43.19			4.83
Ap11(1)_pt25	7.52	55.23				1.34	1.90				34.02

Tab. 2.12. The results of the Ap 12 sample microanalysis

Sample	C	N	O	F	Na	Mg	Al	Si	P	K	Ca	Ti	Fe	Br
Ap12(1)_pt1	14.39		44.96			1.33	15.32	19.30			4.71
Ap12(1)_pt2	11.85		44.30			1.42	15.14	17.91		2.76	6.62
Ap12(1)_pt3	35.21	7.61	42.61			0.48	4.87	5.92			3.29
Ap12(1)_pt4	13.22		40.84				23.45	18.09			4.41
Ap12(1)_pt5	4.05		38.34		3.46	0.88		22.51				5.16	16.71	8.90
Ap12(1)_pt6	4.03		51.96	1.84	1.42	1.30	14.02	24.23			1.21
Ap12(1)_pt7	5.41		51.75	1.25	0.79	1.06	7.36	22.19		1.18	9.03
Ap12(1)_pt8	9.12		48.32		1.31		9.38	21.78		3.46	6.62
Ap12(1)_pt9	10.17		50.07		1.61	1.50	8.33	22.11		6.20
Ap12(1)_pt10	12.87		52.43			1.17	11.33	22.20
Ap12(1)_pt11	11.27		45.62		1.46	1.53	8.32	20.97			10.83
Ap12(1)_pt12	12.51		49.42	1.98	1.92	1.21	10.79	22.17
Ap12(1)_pt13	6.63		41.12		3.39	1.79	10.58	20.76		2.95	6.20		6.59
Ap12(1)_pt14	8.49		48.82			1.35	8.70	18.65		4.64	9.35
Ap12(1)_pt15	12.36		50.02			1.33	9.42	21.05			5.81
Ap12(1)_pt16	3.48		39.25			6.61	9.19	19.66		5.87			15.94
Ap12(1)_pt17	26.60		46.85				5.67	12.91	1.57		6.39
Ap12(1)_pt18	11.80		47.06		1.95		8.25	21.64			6.11		3.19
Ap12(1)_pt19	16.10		48.79			0.94	11.65	22.53
Ap12(1)_pt20	19.41		43.66		0.84	2.19	5.89	14.34		0.84	3.97		8.85
Ap12(1)_pt21	6.14		49.69		4.62		10.32	23.42			4.73	1.08
Ap12(1)_pt22	12.61		45.70			2.11	10.07	20.12		4.79	4.58
Ap12(1)_pt23	34.43		44.17	0.89	1.12	0.95	4.39	10.41		1.11	2.52
Ap12(1)_pt24	6.09		47.73	1.73	1.96	4.78	4.44	21.27			12.00
Ap12(1)_pt25	5.10		36.82			0.87	4.99	10.88		2.43	2.11	6.69	30.11
Ap12(1)_pt26	11.42		50.66				11.82	20.92			5.19
Ap12(1)_pt27	10.51		43.94		1.32	1.53	11.94	23.46			7.31
Ap12(1)_pt28	12.28		46.00		0.93	1.89	14.55	19.97			4.38
Ap12(1)_pt29	19.43		48.96		1.00	2.70	5.41	15.72		3.10	3.67

3. Oleniegorsk

3.1. Introduction

Oleniegorsk is located in the central part of the northern part of the peninsula, on the way to Murmansk. The city is located on the railway and road. But its history is closely connected with the creation of the station “Olenia” in 1916 when building a railway line [26]. Much of this station has grown with the construction of processing plants in nearby Monchegorsk, followed by discovery near the iron line and construction of mining plants. This resulted in the need to build a mining estate, which over time overturned the town. It received city rights in 1957 [26]. The centre of the city centre is preserved in neoclassical style. There are beautiful avenues, squares, buildings that have the characteristic momentum of this period. Around this building there are numerous large-scale buildings, which today are surrounded by counting 23ty inhabitants of the city. Oleniegorsk location in the northern part of the peninsula makes the climate a bit sharper compared to Murmansk, though it is certainly milder than the Apatite. Probably the January temperatures range between –12°C and July +14°C (the extrapolation of Apatity and Murmansk data).

3.2. Preparirate samples to test

During the fieldwork an inventory of the behavior of plasters and photographic documentation was made. Downloaded plaster samples were taken and then examined by optical microscope and scanning electron microscope (fig. 3.7). Subsequently these samples were examined with ICP-OAS and ASA. The results of these analyzes were processed by mathematical software.

3.3. Results

Field research carried out in Oleniegorsk has shown that especially the strict center with the oldest buildings has its own unique style and climate. The townhouses in question have nice facades, are built with attention to detail, designed squares and alleys have aesthetic character, bringing harmony to the city. This build contrasts with newer blocks that are more eclectic, have no ornamentation and their appearance is standard in the former USSR, unifying the building into one type (fig. 3.5) [3, 14, 16]. They are set up in the same characteristic complexes as in other cities of the region. Today, the city landscape is grayed with insufficient thermal insulation. Unfortunately, the state of preservation of buildings in Oleniegorsk indicates that the best times for this city have passed. Perhaps in the near future it will change, but today, the oldest buildings are often shabby, with only temporary improvements, with apparent damage to the arctic climate. Even worse are the stilted blockhouses, which may

be in better technical condition than brick buildings, but their view does not add to the charm of the city.

Microscopic studies have shown a variety of plaster samples. Mineral ornaments were identified in samples 01, 03, 04, 06, 08, 09, 11–14 and in specimen 07 fragments of slag, and paint (samples 06 and 14 red, Figure 3.6). In addition, solid impurities (samples 01–04, 09, 10) and metallic dust were found (samples 01–03, 07, 08–11, 13, 14). In samples 03, 08 were visible plants (algae, moss). In addition, samples of paint 02, 05, 06 were spotted. Barite precursors (sample 02) and carbonate (sample 10) were also identified.

Microelectrode experiments using the EDS have shown that a high content of carbon compounds was found in samples 07 and 11. In addition, the sulfur compounds (in samples 02, 04.05, 7.09, 10.12, 13), chlorine , 07.08, 10) and phosphorus (in samples 01.06,08,09,12). The following metals were also found: iron (all samples), titanium (samples 03, 05-09 and 11), zinc (sample 11), and dopants V (sample 02) and Ir, Tb (sample 12). Studies on cumulated pollutants (Figure 3.1) show that most of them are found in samples 07 and 12 respectively from the intersection of 7 Parkova St, crossing of Molodiezhnyi Bul and Vostochnaya. In addition, relatively large amounts of contaminants were found in samples 08, 09, and 11, respectively, from 3 Parkova St, 46 Soviecka St, 13 Stroiteln St (fig 3.8, tab 3.1–3.14).

Ole01 Ole02 Ole03 Ole04 Ole05 Ole06 Ole07 Ole08 Ole09 Ole10 Ole11 Ole12 Ole13 Ole14

C S Cl P Fe Ti Zn V Ir Tb

Fig. 3.1. Compilation of types of pollutants in the tested plaster samples from Oleniegorska

Geochemical investigations of plaster samples using ICP-OAS and ASA showed some variation (fig. 3.2). Analyzes of the dopants of metals allow to determine their distribution in the studied regions of the city. In the case of zinc the highest contents were found in samples 08 and 14 where they reached the value of 300 ppm. These samples were taken from the neighborhood of

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