Влияние строения субстрата
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kотн |
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kотн |
CH =CH-CH -Cl |
1 |
(CH |
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C-Cl |
4.104 |
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2 |
2 |
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3 |
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3 |
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CH -CH=CH-CH -Cl |
2.103 |
Ph-CH(CH |
)-Cl |
8.104 |
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3 |
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2 |
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3 |
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(CH ) |
C=CH-CH -Cl |
3.106 |
Ph |
C(CH )-Cl |
4.107 |
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3 2 |
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2 |
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2 |
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3 |
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CH =CH-C(CH |
) |
-Cl |
107 |
Ph |
C-Cl |
2.1010 |
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2 |
3 |
2 |
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3 |
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(CH3)2CH-Cl |
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0,1 |
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19
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kотн |
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kотн |
CH =CH-CH -Cl |
1 |
(CH |
) |
C-Cl |
4.104 |
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2 |
2 |
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3 |
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3 |
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CH -CH=CH-CH |
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-Cl |
2.103 |
Ph-CH(CH |
)-Cl |
8.104 |
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3 |
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2 |
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3 |
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(CH ) |
C=CH-CH -Cl |
3.106 |
Ph |
C(CH )-Cl |
4.107 |
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3 2 |
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2 |
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2 |
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3 |
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CH =CH-C(CH |
) |
-Cl |
107 |
Ph |
C-Cl |
2.1010 |
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2 |
3 |
2 |
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3 |
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(CH3)2CH-Cl |
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0,1 |
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20
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kотн |
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kотн |
CH =CH-CH -Cl |
1 |
(CH |
) |
C-Cl |
4.104 |
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2 |
2 |
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3 |
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3 |
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CH -CH=CH-CH -Cl |
2.103 |
Ph-CH(CH |
)-Cl |
8.104 |
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3 |
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2 |
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3 |
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(CH ) |
C=CH-CH -Cl |
3.106 |
Ph |
C(CH )-Cl |
4.107 |
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3 2 |
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2 |
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2 |
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3 |
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CH =CH-C(CH |
) |
-Cl |
107 |
Ph |
C-Cl |
2.1010 |
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2 |
3 |
2 |
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3 |
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(CH3)2CH-Cl |
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0,1 |
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21
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kотн |
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kотн |
CH =CH-CH -Cl |
1 |
(CH |
) |
C-Cl |
4.104 |
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2 |
2 |
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3 |
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3 |
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CH -CH=CH-CH -Cl |
2.103 |
Ph-CH(CH |
)-Cl |
8.104 |
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3 |
2 |
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3 |
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(CH ) |
C=CH-CH -Cl |
3.106 |
Ph |
C(CH )-Cl |
4.107 |
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3 2 |
2 |
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2 |
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3 |
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CH =CH-C(CH ) |
-Cl |
107 |
Ph |
C-Cl |
2.1010 |
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2 |
3 2 |
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3 |
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(CH3)2CH-Cl |
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0,1 |
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22
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kотн |
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kотн |
CH =CH-CH -Cl |
1 |
(CH |
) |
C-Cl |
4.104 |
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2 |
2 |
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3 |
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3 |
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CH -CH=CH-CH -Cl |
2.103 |
Ph-CH(CH |
)-Cl |
8.104 |
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3 |
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2 |
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3 |
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(CH ) |
C=CH-CH -Cl |
3.106 |
Ph |
C(CH )-Cl |
4.107 |
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3 2 |
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2 |
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2 |
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3 |
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CH =CH-C(CH |
) |
-Cl |
107 |
Ph |
C-Cl |
2.1010 |
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2 |
3 |
2 |
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3 |
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(CH3)2CH-Cl |
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0,1 |
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23
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kотн |
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kотн |
CH2=CH-CH2-Cl |
1 |
(CH3)3C-Cl |
4.104 |
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CH -CH=CH-CH -Cl |
2.103 |
Ph-CH(CH |
)-Cl |
8.104 |
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3 |
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2 |
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3 |
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(CH ) |
C=CH-CH -Cl |
3.106 |
Ph |
C(CH )-Cl |
4.107 |
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3 2 |
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2 |
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2 |
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3 |
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CH =CH-C(CH |
) |
-Cl |
107 |
Ph |
C-Cl |
2.1010 |
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2 |
3 |
2 |
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3 |
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(CH3)2CH-Cl |
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0,1 |
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24
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kотн |
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kотн |
CH =CH-CH -Cl |
1 |
(CH |
) |
C-Cl |
4.104 |
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2 |
2 |
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3 |
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3 |
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CH -CH=CH-CH -Cl |
2.103 |
Ph-CH(CH )-Cl |
8.104 |
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3 |
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2 |
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3 |
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(CH ) |
C=CH-CH -Cl |
3.106 |
Ph |
C(CH )-Cl |
4.107 |
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3 2 |
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2 |
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2 |
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3 |
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CH =CH-C(CH |
) |
-Cl |
107 |
Ph |
C-Cl |
2.1010 |
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2 |
3 |
2 |
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3 |
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(CH3)2CH-Cl |
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0,1 |
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25
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kотн |
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kотн |
CH =CH-CH -Cl |
1 |
(CH |
) |
C-Cl |
4.104 |
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2 |
2 |
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3 |
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3 |
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CH -CH=CH-CH -Cl |
2.103 |
Ph-CH(CH )-Cl |
8.104 |
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3 |
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2 |
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3 |
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(CH3)2C=CH-CH2-Cl |
3.106 |
Ph2C(CH3)-Cl |
4.107 |
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CH =CH-C(CH |
) |
-Cl |
107 |
Ph |
C-Cl |
2.1010 |
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2 |
3 |
2 |
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3 |
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(CH3)2CH-Cl |
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0,1 |
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26
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kотн |
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|
kотн |
CH =CH-CH -Cl |
1 |
(CH |
) |
C-Cl |
4.104 |
|||
2 |
2 |
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3 |
3 |
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CH -CH=CH-CH -Cl |
2.103 |
Ph-CH(CH |
)-Cl |
8.104 |
||||
3 |
2 |
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3 |
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(CH ) |
C=CH-CH -Cl |
3.106 |
Ph |
C(CH )-Cl |
4.107 |
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3 2 |
2 |
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2 |
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3 |
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CH2=CH-C(CH3)2-Cl |
107 |
Ph3C-Cl |
2.1010 |
|||||
(CH3)2CH-Cl |
0,1 |
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27
Чем лучше доноры и чем их больше в карбокатионе,
тем быстрее идёт реакция SN1
X-C6H4-CHPh-Cl -4,26 X-C6H4-C(CH3)2-Cl -4,54
+ H2O
R Cl 
R OH
Me2CO, 80%
28