Topic №7: The surface phenomena on border of phases division. Chromatography.Application in medicine.
Basic questions:
1. Energy of surface phenomena. Surface tension.The influence of the different factors of surface tension.
2. Sorption and its kinds.
3. Surface active substances. Rule of Traube-Duclo.
4. Surface in active substances.
5. Gibb’s equation. Gibb’s isotherm of surface tension.
6. Orientation of molecule in surface layer. Longmuir paling.
7. Langmuir equation. Adsorption isotherm of Longmuir.
8. Adsorption on solid adsorbent. Iono change adsorption 9.Chromatography and its essence. Classification of chromatography method.
10. Biological role of surface phenomena, its significance in medicine and in biology.
1)Energy of surface phenomenon. Surface tension.The influence of the different factors of surface tension.
Surface tension is a contractive tendency of the surface of a liquid that allows it to resist an external force. It is revealed, for example, in the floating of some objects on the surface of water, even though they are denser than water, and in the ability of some insects (e.g. water striders) to run on the water surface. This property is caused by cohesion of similar molecules, and is responsible for many of the behaviors of liquids.
Surface tension has the dimension of force per unit length, or of energy per unit area. The two are equivalent—but when referring to energy per unit of area, people use the term surface energy—which is a more general term in the sense that it applies also to solids and not just liquids.In materials science, surface tension is used for either surface stress or surface free energy.
Surface energy quantifies the disruption of intermolecular bonds that occur when a surface is created. In the physics of solids, surfaces must be intrinsically less energetically favorable than the bulk of a material (the molecules on the surface have more energy compared with the molecules in the bulk of the material), otherwise there would be a driving force for surfaces to be created, removing the bulk of the material (see sublimation). The surface energy may therefore be defined as the excess energy at the surface of a material compared to the bulk.
Effects of surface tension
Water
Several effects of surface tension can be seen with ordinary water:
A. Beading of rain water on a waxy surface, such as a leaf. Water adheres weakly to wax and strongly to itself, so water clusters into drops. Surface tension gives them their near-spherical shape, because a sphere has the smallest possible surface area to volume ratio.
B. Formation of drops occurs when a mass of liquid is stretched. The animation shows water adhering to the faucet gaining mass until it is stretched to a point where the surface tension can no longer bind it to the faucet. It then separates and surface tension forms the drop into a sphere. If a stream of water were running from the faucet, the stream would break up into drops during its fall. Gravity stretches the stream, then surface tension pinches it into spheres.
C. Flotation of objects denser than water occurs when the object is non wettable and its weight is small enough to be borne by the forces arising from surface tension. For example, water striders use surface tension to walk on the surface of a pond. The surface of the water behaves like an elastic film: the insect's feet cause indentations in the water's surface, increasing its surface area.
D. Separation of oil and water (in this case, water and liquid wax) is caused by a tension in the surface between dissimilar liquids. This type of surface tension is called "interface tension", but its physics are the same.
E. Tears of wine is the formation of drops and rivulets on the side of a glass containing an alcoholic beverage. Its cause is a complex interaction between the differing surface tensions of water and ethanol; it is induced by a combination of surface tension modification of water by ethanol together with ethanol evaporating faster than water.
