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112 COMPOSITE MATERIALS FOR AIRCRAFT STRUCTURES

4.4.6 Polyetherimide

Polyetherimide (PEI) is an amorphous, high-performance thermoplastic. The amorphous structure of PEI contributes to its dimensional stability, low shrinkage, and highly isotropic mechanical properties compared with most crystalline polymers. The high Tg allows PEI to be used intermittently at 200 °C. Un-reinforced PEI is one of the strongest engineering amorphous thermoplastics and offers very good mechanical properties but has the forming disadvantage of very high viscosity in the molten state. Despite being amorphous, PEI is very tolerant to solvents and environmental exposure and resists a broad range of chemicals, including most hydrocarbons, non-aromatic alcohols, and fully halogenated solvents. The molecular structure of some of the polyimide resins is depicted in Figure 4.20.

References

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Polymer Engineering & Science, Vol. 19, 1979, pp. 676-682.

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11Reinhart, T. J., (ed.), Composite Engineered Materials Handbook, Vol. 1, American Society for Metals International, 1993, pp. 100-101.

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