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Cullity B.D. Introduction to Magnetic Materials. Second Edition (2008)

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14.14 APPLICATIONS

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14.14.2Mechanical-to-Electrical

If the flux through a winding is changed, an emf will be induced in that winding. The flux change can be effected by any mechanically produced relative motion of a magnet and the winding. This principle is the basis for devices like the magneto and the microphone. The magneto consists of a magnet rotating within an iron core carrying a winding. It is used to produce the sparks for ignition in small gasoline engines, such as those used in power lawn mowers and outboard motors.

The magnetic microphone is simply the inverse of the loudspeaker. It is rarely used, except in some simple communication systems where the loudspeaker also serves as the microphone.

14.14.3Microwave Equipment

Included here is equipment both for communications and radar. The devices involved bear such names as magnetron and traveling wave tube, and the details of their operation are matters for a specialist. In some traveling wave tubes for military and radar applications, the requirements are so severe that only materials of very high coercivity, like PtCo and SmCo5, are suitable.

14.14.4Wigglers and Undulators

The electron current in a synchrotron emits radiation when it is accelerated into a curved path. This synchrotron radiation is an unwanted power loss and radiation hazard to the people using the electrons, but a valuable source of high-intensity X-radiation of adjustable frequency to the solid-state physicist and similar scientific workers. The intensity and characteristics of the synchrotron radiation can be enhanced by passing the electron beam through an array of permanent magnets that force the electron beam to accelerate up and down or side to side. Such arrays are known as wigglers and undulators.

14.14.5Force Applications

If either pole of a permanent magnet is brought near a piece of iron, the field of the magnet will magnetize the iron in such a direction that an opposite pole will be, to use the ancient term, “induced” in the iron, and attraction will occur. On the other hand, if like poles of two permanent magnets are brought together, repulsion will result. The calculation of these forces is not easy.

Attraction. If the flat end of a magnet makes good contact with a material of high permeability or with the flat end of a magnet of opposite polarity, the force of attraction between the two is

F ¼

AB2

,

(14:11)

2C4

where in SI units the force F is in newtons, A is the area of contact in m2, B is the flux density in tesla, and C4 ¼ 1. In cgs units, F is in dynes, A in cm2, B in gauss, and C4 ¼ 4p. This equation can be derived by summing the Coulomb forces between all the poles

502 HARD MAGNETIC MATERIALS

Fig. 14.20 Permanent magnet chuck.

assumed to lie on the two surfaces. But it can be understood more simply in another way. Suppose the two pieces are pulled apart to a small distance d, creating a very thin gap. If there is no fringing, the field in this gap is B, and the energy density of the field is B2/8p (cgs units), from Equation 7.43. The work done is Fd and the field energy is (B2/8p)(Ad). If the two are equated, Equation 14.11 follows. This equation holds only when the two pieces are very close together; the attractive force falls off very rapidly as the two are separated.

Attractive forces are exploited in permanent-magnet chucks, which are gripping devices that can be used, for example, to hold steel objects in place for a machining or grinding operation. Naturally, there must be some means of turning off the holding force, and many ingenious ways of doing so have been contrived. The simplest is shown in Fig. 14.20. When the magnet is rotated into the vertical position, the flux is short-circuited by the pole pieces, which have a lower reluctance than the path through the load. Another holding application is the magnetic latch, widely used on kitchen cupboard doors. These are made in large volume at low cost, using ferrite magnets.

Magnets are used as separators. The most common application is the removal of scrap iron and steel from liquids and powdered or granular materials, such as grain or sugar. Loose nuts, bolts, nails, and wire are ubiquitous in any environment inhabited by modern man. Other uses are in the separation of ferromagnetic items from trash, and the separation of mineral ores on the basis of their magnetic permeabilities. A related use is the protection of cattle from ingested iron. Cattle can pick up along with their food bits of baling wire, nails, and other pieces of iron. This sharp-edged material lodges in the cow’s second stomach, which it can irritate or puncture, leading to infection and other complications, a malady known as “hardware disease.” The remedy is a cylindrical magnet of alnico or ferrite, 2–3 inches (5–7.5 cm) long and 12 inch (1.25 cm) in diameter, with rounded ends, and protected with a thin plastic coating. It is simply dropped down the cow’s throat; it lodges in the second stomach and remains there for the life of the cow, attracting and holding any iron that enters.

Magnets can be used as large-scale positioners to transmit linear or rotary motion across a solid barrier. This is useful for positioning equipment inside a sealed space, such as a vacuum or controlled atmosphere chamber. Many designs have been proposed and constructed.

14.14 APPLICATIONS

503

Fig. 14.21 Floating globe using magnetic suspension with feedback.

14.14.6Magnetic Levitation

For centuries there had been dreams of magnetic levitation, i.e., the stable suspension in the air of a body made of iron or other magnetic material, without physical contact, by an artful arrangement of magnets exerting the proper attraction and repulsion. But such hopes were dashed in 1839 when S. Earnshaw [Trans. Cambridge Phil. Soc., 7 (1837–1842) p. 97] proved that it could not be done. His theorem relates to both electrostatic and magnetostatic forces, or to any system of particles which exert forces on one another varying inversely as the square of the distance. For magnetic systems, Earnshaw’s theorem may be stated as follows: Stable levitation of one body by one or more other bodies is impossible, if all bodies in the system have a permeability greater than 1.

Stable levitation can be achieved for a positive permeability material if a position detector and feedback system are employed so that the force acting on the floating object is continuously adjusted, usually by varying the current through an electromagnet. This is the basis for various floating novelty items (see Fig. 14.21) as well as for nearly zero-friction suspensions for various kinds of rotating instruments and machines.

If diamagnetic materials are included in the system, stable levitation becomes possible without power input. Levitation of this kind is easiest with a perfect diamagnet, namely, a superconductor (Chapter 16). Figure 14.22 shows a bar magnet floating over the slightly concave surface of superconducting lead at 4K. The magnet is in effect supported by its own field, which cannot penetrate into the lead.

The permeability of a superconductor is zero, and there are many diamagnetic materials with permeabilities slightly less than unity. But there are no diamagnetic materials with intermediate values of m, like 20.5. This means that only very light bodies, a few grams

504 HARD MAGNETIC MATERIALS

Fig. 14.22 Bar magnet suspended over a superconducting plate.

in weight, can be stably levitated at room temperature with the help of ordinary diamagnetic materials, like graphite or bismuth, because their flux-repelling powers are so feeble.

Quite large weights can be supported by the repulsion between permanent magnets, the lower one fixed to a base and the upper one to the underside of the load. Some lateral constraint is needed to make the load stable, but it need not be strong. The magnets must have high coercivity. Barium ferrite and rare-earth magnets are well suited to this application since they can be made in flat pieces of fairly large area, magnetized in the thickness direction. G. R. Polgreen has written a book mainly devoted to this subject [New Applications of Permanent Magnets, MacDonald (1966)].

PROBLEMS

14.1 Show that the slope of the load line of a permanent magnet circuit is given by

Bm ¼ 1 Nd (SI):

Hm Nd

14.2Given two iron rods, identical except that one is magnetized lengthwise and the other is demagnetized, how could you tell them apart without using any experimental apparatus?

14.3A cobalt steel magnet with (BH)max ¼ 1.0 MGOe is 12 cm3 in volume. If the steel is replaced by an alnico magnet with (BH)max ¼ 7.5 MGOe, what volume of alnico will be required to produce the same field in the same air gap? What volume of material is required if the alnico is replaced by FeNdB, with (BH)max ¼ 40 MGOe? (This is actually not a very useful comparison, because the very high coercive

fields of rare-earth magnets permit geometries not possible with steel or alnico.)

CHAPTER 15

MAGNETIC MATERIALS FOR RECORDING AND COMPUTERS

15.1INTRODUCTION

Magnetic materials are an essential feature of digital data storage, and have served as the basis for systems of analog audio and video recording. Magnetic materials have been used in the central processing units of computers, and although for many years magnetic CPUs have been replaced by semiconductor materials in this role, magnetic materials may be making a return.

The materials and properties that are useful in these applications do not generally fall neatly into the usual categories of soft and hard magnetics. Furthermore, the increasing miniaturization of computer components means that the magnetic materials in computer and recording devices are commonly made and used in the form of thin films. For these reasons, it seems appropriate to consider magnetic materials for recording and computers in a separate chapter.

Nicola Spaldin has written a text on magnetic materials emphasizing computer applications: Magnetic Materials, Fundamentals and Device Applications, Cambridge University Press (2003).

15.2MAGNETIC RECORDING

15.2.1Analog Audio and Video Recording

Sound was first recorded on a magnetic medium—a steel wire—in 1898, but magnetic audio recording was not seriously developed until the 1930s. This early work was done mostly in Germany, especially during World War II. The recording medium was no longer wire or metal ribbon, but a plastic tape coated with a flexible magnetic layer.

Introduction to Magnetic Materials, Second Edition. By B. D. Cullity and C. D. Graham Copyright # 2009 the Institute of Electrical and Electronics Engineers, Inc.

505

506 MAGNETIC MATERIALS FOR RECORDING AND COMPUTERS

In addition to better sound quality, magnetic tape recordings could extend over much longer unbroken time periods, and were less subject to mechanical damage, and occupied less space than the gramophone-style (disk and needle) recordings they replaced. Magnetic tape can also be rerecorded.

Tape recording equipment rapidly came into use by radio studios and networks in the 1950s. Not only could entire programs be prerecorded, but errors could be edited out. Magnetic recording as a consumer product only became popular with the introduction of the audio tape cassette in 1963. Prerecorded music tape cassettes as well as blank tape cassettes on which the user could make recordings were sold in large quantities and remain available in 2007. However, starting about 1980, the digital audio compact disk, or CD, began to replace the cassette tape as a medium for prerecorded music, and recordable CDs are now (2007) also common.

Video recording required modifications in tape recording technology, because of the much greater amount of information to be stored per unit of time. Both the magnetic material used for recording and the geometry of the recording path were changed, and there was a famous and destructive battle between two different video cassette formats, Betamax and VHS, which was won by VHS largely because it provided longer recording times in its early versions.

15.3PRINCIPLES OF MAGNETIC RECORDING

The basic arrangement for analog magnetic recording on tape, as well as for digital magnetic recording on tape and on disk, is shown in Fig. 15.1. A flexible or rigid substrate coated with a magnetic layer is moved past a write head, which is effectively a miniature electromagnet. A current in the winding of the write head magnetizes the head material, which creates a magnetic field in the head gap. The fringing field from the gap magnetizes the tape material in a pattern that reproduces the information to be recorded. The information is recorded in a stripe, called a track, running parallel to the length of the tape or in a circular path on a disk.

To read back the recorded information, the recorded track passes under a read head, which is similar to the write head. In low-cost audio recorders, the same head may be used for both reading and writing. The fringing magnetic field from the recorded tape magnetizes the read head as it passes by the head gap, and the changing magnetization in the

Fig. 15.1 Principle of magnetic recording.

15.3 PRINCIPLES OF MAGNETIC RECORDING

507

head generates a signal voltage in the head winding. This voltage contains the recorded information, and can be amplified to recreate the recorded sound or video. Note that since the read head coil voltage is proportional to the time derivative of the flux change in the head, the amplification must include an integration step.

15.3.1Materials Considerations

The write and read heads must be high-permeability, low-coercivity magnetic materials capable of operating at reasonably high frequencies. Originally, very thin permalloy laminations were used, and amorphous alloys have been tried. The usual choice for analog recording, however, is a magnetically soft ferrite.

The recording medium must have low enough coercivity to be written on, high enough coercivity to resist local demagnetizing fields and retain a recorded pattern indefinitely, and high enough magnetization to provide a readable signal to the read head. The usual choice for audio recording is g-Fe2O3 (maghemite) particles in a flexible matrix. The packing fraction of the particles in the coating is about 0.4. The crystal and spin structure of g-Fe2O3 have already been described (Section 6.6); it is a ferrimagnetic spinel with ss ¼ 76 emu/g or A m2/kg. (Ms ¼ 390 emu/cm3 or 3.9 104 A/m). The oxide is in the form of elongated single-domain particles, about 0.1 mm in diameter and with a length/ diameter ratio near 6. They owe their coercivity, 250–300 Oe, to shape anisotropy. Since this value is only about a tenth of that expected for coherent rotation (2p Ms ¼ 2450 Oe), the magnetization of these particles must reverse incoherently. The particles in the tape coating are aligned by a field during the coating process so that their long axes are aligned parallel with the length of the tape; this is done in order to make the remanence, after magnetization in that direction, as large as possible.

The elongated oxide particles are made from hydrated ferric oxide (a-FeO . OH) particles, which are already elongated, in the following steps: (1) dehydration to hematite (a-Fe2O3); (2) reduction by hydrogen at 4008C to magnetite (Fe3O4); and (3) careful oxidation at about 2508C to g-Fe2O3. The addition of cobalt, either in solid solution or as an adsorbed surface layer, has beneficial effects on the magnetic properties.

Chromium dioxide (CrO2) is commonly used for video recording tape, and also for higher grades of audio recording tape. This material is one of nature’s rarities, a ferromagnetic oxide (Section 4.5). It has ss equal to 90–100 emu/g or A m2/kg, depending on how it is made, and fine particles can be prepared with greater elongations and smoother surfaces than g-Fe2O3. Its coercivity is therefore higher, about 400 Oe.

Audio tape has been made using Fe or FeCo particles instead of oxide particles, and also using a continuous magnetic metal alloy layer, usually based on Co.

15.3.2ac Bias

To minimize distortion due to the nonlinear and irreversible nature of the hysteresis loop of the recording medium, a sinusoidal current at about 100 kHz is superimposed on the recording signal current, and the combined signal is fed to the recording head. Figure 15.2 illustrates this combined signal. The ac bias field is at a higher frequency than the highest frequency to be recorded, and of sufficient magnitude to drive the material of the tape near magnetic saturation. Under these conditions, a section of tape passing under the write head sees a strong ac field superimposed on an almost constant dc field, which is the signal to be recorded. The resulting remanent magnetization in the tape, after the

508 MAGNETIC MATERIALS FOR RECORDING AND COMPUTERS

Fig. 15.2 Combined bias signal (light line) and recorded signal (heavy line) fed to the write head. This signal corresponds to the field in the head gap, which magnetizes the tape.

tape has left the head, is very nearly proportional to the value of the signal to be recorded. The strength of the ac bias current must be adjusted to match the properties of the magnetic material of the tape; some recorders provide a manual switch to adjust the bias and some use a system of coded notches in the audio cassette to automatically set the correct bias.

15.3.3Video Recording

The recording of analog video signals requires much higher recording density than audio. Successful video recording required the use of better recording material, usually CrO2, as well as a different recording geometry. By the use of a fairly complex tape path through the machine, and a pair of write heads mounted in a rapidly rotating drum, video information is recorded in a series of diagonal tracks across the tape, as in Fig. 15.3. Each diagonal track carries the information for one sweep of the electron beam across the face of the picture tube.

Just as analog audio recording was largely replaced by digital audio recording in the form of the CD, the same thing happened about ten years later to video recording, in the form of the digital video (or versatile) disk (DVD). Both the CD and the DVD exist in three forms, the nonwriteable, prerecorded; the writeable but not rewritable; and the rewriteable or rerecordable versions.

Magnetic recording on tape and on disk are physically almost identical processes. On tape (except video tape), the recorded tracks run parallel to the tape axis, so skipping over

Fig. 15.3 Recorded pattern on a video tape, produced by a pair of rotating write heads.

15.4 MAGNETIC DIGITAL RECORDING

509

unwanted information requires speeding up and then slowing down the tape drive—a slow operation. On disks, the recorded tracks are a series of concentric circles, and the heads can jump very quickly from track to track in order to recover a desired string of data.

15.4MAGNETIC DIGITAL RECORDING

It is first necessary to distinguish between the digital recording of analog data, and the digital recording of digital data. In the former, the analog signal is sampled at a frequency higher than the maximum frequency to be recorded, and each sample point is converted to a numerical value, as suggested in Fig. 15.4. This string of numbers, coded in 1s and 0s, must be recorded, and must be retrievable at a rate that exactly matches the original signal. It is desirable to make the recorded data occupy the smallest possible space, but not to increase the speed of the playback. The recorded data is usually in the form of fairly long unbroken stretches (complete songs or video sequences).

Direct recording of digital data is somewhat different. In addition to the motivation to minimize the volume occupied by the recording, there is pressure to speed up the recording and the reading processes. Whether the recorded information is a program or data or a picture, the user wants it to be loaded and ready to use in the shortest possible time. The information may be in very short strings, very long strings, or anything in between.

In either case, the information is recorded as a string of 1s and 0s, which greatly simplifies the recording process. An ac bias signal is no longer needed, and the recorded signal need not be proportional to the input signal. The standard method is to simply magnetize short bits of the recording surface, approximately equal in length to the gap in the recording head, in a direction parallel or antiparallel to the track length. This is known as longitudinal recording. In reading back the information, the magnetic flux at the boundary between bits magnetized in opposite directions is detected; these are called flux reversals.

In the following sections, we will deal with digital recording of digital data.

15.4.1Magnetoresistive Read Heads

As recorded track widths grew narrower and bit lengths got shorter, the flux available at a flux reversal was no longer sufficient to produce a reliable signal in a conventional inductive read head. The solution lay in the phenomenon of magnetoresistance, which is the change

Fig. 15.4 Digitizing of analog information.

510 MAGNETIC MATERIALS FOR RECORDING AND COMPUTERS

in resistance of a material when subjected to a magnetic field. All materials show magnetoresistance, but the effect is largest, and also anisotropic (depending on the relative directions of the field and the current) in ferromagnets. So thin films of Ni–Fe alloy were used to detect flux reversals in the first magnetoresistive read heads. The change in resistance of the magnetic layer when a saturating field is applied is about 2%.

A different head structure evolved after the discovery of the giant magnetoresistive effect, or GMR. This phenomenon was first studied in multilayer films of alternating layers of Fe and Cr. There is a long-range exchange through the Cr layer, which acts to couple the moments of the Fe layers either parallel or antiparallel, depending on the thickness of the Cr. If the coupling is antiparallel, or antiferromagnetic, the Fe layers will be magnetized in alternating opposite directions in zero field, but a sufficiently strong applied field can align all the moments in one direction. The electrical resistance of the stack is substantially lowered when the moments are forced to lie parallel. This is the giant magnetoresistive effect; it is not a property of a material, but of a stack of thin films of alternating composition.

The first GMR experiments were done with the samples at low temperature, and required strong applied fields (kOe) to switch the magnetization directions. Extensive development work, drawing on both thin-film deposition technology and on the quantum theory of solids, led to a relatively simple practical device, operating at room temperature, which is known as the spin valve. An example is shown in Fig. 15.5. Two ferromagnetic NiFe layers are separated by a layer of copper, which provides weak anitferromagnetic coupling between the two NiFe layers. One of the NiFe layers is in exchange contact with an antiferromagnetic layer (FeMn or IrMn), which holds the magnetization direction of the adjacent NiFe fixed in fields up to about 100 Oe (8 kA/m). This is called the fixed layer or the reference layer and the other NiFe layer is the free layer. A small field applied to this composite structure will rotate the direction of magnetization of the free layer, which will change the electrical resistance of the device.

The GMR spin valves used as read heads in hard disk drives are more complex. The ferromagnetic layers are themselves layered and there may be a permanent magnet layer to hold the magnetic direction of the fixed layer in a desired direction. The reference layer is actually a triple layer of CoFe–Ru–CoFe, with the Ru layer thickness chosen to provide strong antiferromagnetic coupling between the CoFe layers. This results in a strongly directional CoFe layer in a substructure with no net magnetization. There are also layers to carry the current through the head to measure the resistance change, and “seed” layers to assure good adhesion of the films. The structure may have up to a dozen

Fig. 15.5 Basic structure of a spin valve.