шпора по физике за первый семестр / реальные газы

яю 50;L=K5 307K. @8 42865=88 <>;5:C;K 240;8 >B AB5=>: A>AC40, 2 :>B>@>< 70:;NG5= 307, =0 =55 459AB2CNB A8;K ?@8BO65=8O A>A54=8E <>;5:C;, => @02=>459AB2CNI0O 2A5E MB8E A8; 2 A@54=5< @02=0 =C;N, B.:. <>;5:C;C A> 2A5E AB>@>= >:@C605B 2 A@54=5< >48=0:>2>5 G8A;> A>A5459. @8 ?@81;865=88 =5:>B>@>9 <>;5:C;K : AB5=:5 A>AC40 2A5 >AB0;L=K5 <>;5:C;K 3070 >:07K20NBAO ?> >4=C AB>@>=C >B =55 8 @02=>459AB2CNI0O 2A5E A8; ?@8BO65=8O >:07K205BAO =0?@02;5==>9 >B AB5=:8 A>AC40 2=CB@L 3070. -B> ?@82>48B : B><C, GB> C<5=LH05BAO 8<?C;LA, ?5@540205<K9 <>;5:C;>9 AB5=:5 A>AC40.  @57C;LB0B5 402;5=85 3070 =0 AB5=:8 A>AC40 C<5=LH05BAO ?> A@02=5=8N A B5<, :0:8< >=> 1K;> 1K 2 >BACBAB285 A8; ?@8BO65=8O <564C <>;5:C;0<8: p = p 8450;L=>3> + delta p. <5AB> C@02=5=8O 8450;L=>3> 3070 ?>;CG05< p + delta p = nkT ; delta p = a/V(AB.2);

45 a  ?>AB>O==0O, 7028AOI0O >B 2840 3070. ;O >4=>3> <>;O 3070 ?>;CG05< p+a/V(AB.2) = R T / V ; >?@02:0: ?@8 ;N1KE 402;5=8OE, >1J5< 3070 =5 <>65B AB0BL @02=K< =C;N. #@02=5=85 0=-45@-00;LA0:

(p + a / V (AB.2)) (V - b) = RT, 345 b  B0: =07K205<K9  70?@5I5==K9 >1J5<